Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II).
In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825718516064452608 |
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| author | Ikmal H, N.A. Suleiman G, N. Khaledi, H. Mohd A, H. |
| author_facet | Ikmal H, N.A. Suleiman G, N. Khaledi, H. Mohd A, H. |
| author_sort | Ikmal H, N.A. |
| collection | UM |
| description | In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)]. |
| first_indexed | 2024-03-06T05:05:43Z |
| format | Article |
| id | um.eprints-1193 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:05:43Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-11932019-01-31T02:28:32Z http://eprints.um.edu.my/1193/ Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). Ikmal H, N.A. Suleiman G, N. Khaledi, H. Mohd A, H. QD Chemistry R Medicine In the title compound, [CuCl(C(14)H(19)N(2)O(2))], the Cu(II) ion is four-coordinated by one deprotonated N,N',O-tridentate Schiff base and one chloride ion in a distorted square-planar geometry. In the crystal, adjacent mol-ecules are linked via C-H⋯Cl and C-H⋯O inter-actions, forming infinite layers parallel to the (100) plane. The structure was determined from a non-merohedrally twined crystal [twin ratio 0.777 (3):0.223 (3)]. International Union of Crystallography 2010 Article PeerReviewed Ikmal H, N.A. and Suleiman G, N. and Khaledi, H. and Mohd A, H. (2010) Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). Acta Crystallographica Section E: Structure Reports Online, 67 (Pt 1). m57. ISSN 1600-5368, DOI 21522575. http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050288/ 21522575 |
| spellingShingle | QD Chemistry R Medicine Ikmal H, N.A. Suleiman G, N. Khaledi, H. Mohd A, H. Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). |
| title | Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). |
| title_full | Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). |
| title_fullStr | Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). |
| title_full_unstemmed | Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). |
| title_short | Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-κN,N',O)copper(II). |
| title_sort | chlorido 2 1 2 morpholino eth yl imino eth yl phenolato κn n o copper ii |
| topic | QD Chemistry R Medicine |
| work_keys_str_mv | AT ikmalhna chlorido212morpholinoethyliminoethylphenolatoknnocopperii AT suleimangn chlorido212morpholinoethyliminoethylphenolatoknnocopperii AT khaledih chlorido212morpholinoethyliminoethylphenolatoknnocopperii AT mohdah chlorido212morpholinoethyliminoethylphenolatoknnocopperii |