Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720113788092416 |
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| author | Halim, S.N.A. Ali, H.M. Ng, S.W. |
| author_facet | Halim, S.N.A. Ali, H.M. Ng, S.W. |
| author_sort | Halim, S.N.A. |
| collection | UM |
| description | In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. |
| first_indexed | 2024-03-06T05:30:04Z |
| format | Article |
| id | um.eprints-11989 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:04Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-119892019-01-29T09:11:26Z http://eprints.um.edu.my/11989/ Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate Halim, S.N.A. Ali, H.M. Ng, S.W. Q Science (General) In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. International Union of Crystallography 2010 Article PeerReviewed Halim, S.N.A. and Ali, H.M. and Ng, S.W. (2010) Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1439-U950. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Halim, S.N.A. Ali, H.M. Ng, S.W. Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title | Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_full | Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_fullStr | Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_full_unstemmed | Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_short | Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_sort | bis n 2 oxo 1h indol 3 ylidene furan2 carbohydrazidato kappa o 3 n o manganese ii n n dimethylformide monosolvate monohydrate |
| topic | Q Science (General) |
| work_keys_str_mv | AT halimsna bisn2oxo1hindol3ylidenefuran2carbohydrazidatokappao3nomanganeseiinndimethylformidemonosolvatemonohydrate AT alihm bisn2oxo1hindol3ylidenefuran2carbohydrazidatokappao3nomanganeseiinndimethylformidemonosolvatemonohydrate AT ngsw bisn2oxo1hindol3ylidenefuran2carbohydrazidatokappao3nomanganeseiinndimethylformidemonosolvatemonohydrate |