Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate
The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O `- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule en...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: |
| _version_ | 1796946330063470592 |
|---|---|
| author | Halim, S.N.A. Ali, H.M. Ng, S.W. |
| author_facet | Halim, S.N.A. Ali, H.M. Ng, S.W. |
| author_sort | Halim, S.N.A. |
| collection | UM |
| description | The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O `- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. |
| first_indexed | 2024-03-06T05:30:04Z |
| format | Article |
| id | um.eprints-11990 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:04Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-119902019-01-29T09:11:43Z http://eprints.um.edu.my/11990/ Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate Halim, S.N.A. Ali, H.M. Ng, S.W. Q Science (General) The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O `- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. International Union of Crystallography 2010 Article PeerReviewed Halim, S.N.A. and Ali, H.M. and Ng, S.W. (2010) Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1438-U938. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Halim, S.N.A. Ali, H.M. Ng, S.W. Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title | Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_full | Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_fullStr | Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_full_unstemmed | Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_short | Bis[N `-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N `,O `]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_sort | bis n 2 oxo 1h indol 3 ylidene thiophene 2 carbohydrazidato kappa o 3 n o zinc ii n n dimethylformide monosolvate monohydrate |
| topic | Q Science (General) |
| work_keys_str_mv | AT halimsna bisn2oxo1hindol3ylidenethiophene2carbohydrazidatokappao3nozinciinndimethylformidemonosolvatemonohydrate AT alihm bisn2oxo1hindol3ylidenethiophene2carbohydrazidatokappao3nozinciinndimethylformidemonosolvatemonohydrate AT ngsw bisn2oxo1hindol3ylidenethiophene2carbohydrazidatokappao3nozinciinndimethylformidemonosolvatemonohydrate |