catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion;...
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| 格式: | 文件 |
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International Union of Crystallography
2010
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| _version_ | 1825720114361663488 |
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| author | Han, Yin-Feng Ng, S.W. |
| author_facet | Han, Yin-Feng Ng, S.W. |
| author_sort | Han, Yin-Feng |
| collection | UM |
| description | In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O-H center dot center dot center dot O hydrogen bonds involving the coordinated and uncoordinated water molecules. |
| first_indexed | 2024-03-06T05:30:04Z |
| format | Article |
| id | um.eprints-11992 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:04Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-119922019-01-31T04:20:00Z http://eprints.um.edu.my/11992/ catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] Han, Yin-Feng Ng, S.W. Q Science (General) In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O-H center dot center dot center dot O hydrogen bonds involving the coordinated and uncoordinated water molecules. International Union of Crystallography 2010 Article PeerReviewed Han, Yin-Feng and Ng, S.W. (2010) catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1431-U884. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Han, Yin-Feng Ng, S.W. catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] |
| title | catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] |
| title_full | catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] |
| title_fullStr | catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] |
| title_full_unstemmed | catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] |
| title_short | catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] |
| title_sort | catena poly tetraaqua 3 5 dinitro 4 oxidopyridine n oxide kappa o 1 neodymium iii mu oxalato kappa o 4 1 o 2 o 1 o 2 tetrahydrate |
| topic | Q Science (General) |
| work_keys_str_mv | AT hanyinfeng catenapolytetraaqua35dinitro4oxidopyridinenoxidekappao1neodymiumiiimuoxalatokappao41o2o1o2tetrahydrate AT ngsw catenapolytetraaqua35dinitro4oxidopyridinenoxidekappao1neodymiumiiimuoxalatokappao41o2o1o2tetrahydrate |