mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate
The two Ni-II atoms in the title complex, [Ni-2(CN)(4)-(C16H36N4)]center dot C3H7NO center dot 0.5H(2)O, are bridged by a cyanide ion. The macrocycle folds around one Ni-II atom, which is five-coordinated in an NiN5 square-pyramidal geometry. The other Ni-II atom is surrounded by the cyanide ions in...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720114742296576 |
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| author | Jiang, Hai-Ming Ng, S.W. |
| author_facet | Jiang, Hai-Ming Ng, S.W. |
| author_sort | Jiang, Hai-Ming |
| collection | UM |
| description | The two Ni-II atoms in the title complex, [Ni-2(CN)(4)-(C16H36N4)]center dot C3H7NO center dot 0.5H(2)O, are bridged by a cyanide ion. The macrocycle folds around one Ni-II atom, which is five-coordinated in an NiN5 square-pyramidal geometry. The other Ni-II atom is surrounded by the cyanide ions in an NiN4 square-planar geometry. The dimethylformamide solvent molecule is disordered over two positions in a 0.62 (1):0.38 (1) ratio and the water molecule is disordered about a center of inversion. The dinuclear molecule and solvent molecules are linked by N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional network. |
| first_indexed | 2024-03-06T05:30:05Z |
| format | Article |
| id | um.eprints-11994 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:05Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-119942019-01-31T04:26:30Z http://eprints.um.edu.my/11994/ mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate Jiang, Hai-Ming Ng, S.W. Q Science (General) The two Ni-II atoms in the title complex, [Ni-2(CN)(4)-(C16H36N4)]center dot C3H7NO center dot 0.5H(2)O, are bridged by a cyanide ion. The macrocycle folds around one Ni-II atom, which is five-coordinated in an NiN5 square-pyramidal geometry. The other Ni-II atom is surrounded by the cyanide ions in an NiN4 square-planar geometry. The dimethylformamide solvent molecule is disordered over two positions in a 0.62 (1):0.38 (1) ratio and the water molecule is disordered about a center of inversion. The dinuclear molecule and solvent molecules are linked by N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Jiang, Hai-Ming and Ng, S.W. (2010) mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1467-U1212. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Jiang, Hai-Ming Ng, S.W. mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate |
| title | mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate |
| title_full | mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate |
| title_fullStr | mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate |
| title_full_unstemmed | mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate |
| title_short | mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate |
| title_sort | mu cyanido 1 2 kappa n 2 c tricyanido 2 kappa c 3 rac 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane 1 kappa n 4 n n n dinickel ii n n dimethylformamide monosolvate hemihydrate |
| topic | Q Science (General) |
| work_keys_str_mv | AT jianghaiming mucyanido12kappan2ctricyanido2kappac3rac557121214hexamethyl14811tetraazacyclotetradecane1kappan4nnndinickeliinndimethylformamidemonosolvatehemihydrate AT ngsw mucyanido12kappan2ctricyanido2kappac3rac557121214hexamethyl14811tetraazacyclotetradecane1kappan4nnndinickeliinndimethylformamidemonosolvatehemihydrate |