mu-Cyanido-1:2 kappa N-2:C-tricyanido-2 kappa C-3(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1 kappa N-4,N `,N `',N `'')dinickel(II) N,N-dimethylformamide monosolvate hemihydrate
The two Ni-II atoms in the title complex, [Ni-2(CN)(4)-(C16H36N4)]center dot C3H7NO center dot 0.5H(2)O, are bridged by a cyanide ion. The macrocycle folds around one Ni-II atom, which is five-coordinated in an NiN5 square-pyramidal geometry. The other Ni-II atom is surrounded by the cyanide ions in...
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| Format: | Article |
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International Union of Crystallography
2010
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