(2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot cente...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720115321110528 |
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| author | Ou, Guang-Chuan Ng, S.W. |
| author_facet | Ou, Guang-Chuan Ng, S.W. |
| author_sort | Ou, Guang-Chuan |
| collection | UM |
| description | In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions. |
| first_indexed | 2024-03-06T05:30:05Z |
| format | Article |
| id | um.eprints-11997 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:05Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-119972019-01-31T05:10:59Z http://eprints.um.edu.my/11997/ (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate Ou, Guang-Chuan Ng, S.W. Q Science (General) In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions. International Union of Crystallography 2010 Article PeerReviewed Ou, Guang-Chuan and Ng, S.W. (2010) (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1468-U1223. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Ou, Guang-Chuan Ng, S.W. (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate |
| title | (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate |
| title_full | (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate |
| title_fullStr | (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate |
| title_full_unstemmed | (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate |
| title_short | (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate |
| title_sort | 2 carboxyacetato kappa o 2 1 o 1 rac 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane kappa n 4 n n n nickel ii perchlorate acetonitrile solvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT ouguangchuan 2carboxyacetatokappao21o1rac557121214hexamethyl14811tetraazacyclotetradecanekappan4nnnnickeliiperchlorateacetonitrilesolvate AT ngsw 2carboxyacetatokappao21o1rac557121214hexamethyl14811tetraazacyclotetradecanekappan4nnnnickeliiperchlorateacetonitrilesolvate |