(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate
The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate...
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| Format: | Article |
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International Union of Crystallography
2010
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| author | Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. |
| author_facet | Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. |
| author_sort | Zhang, Kou-Lin |
| collection | UM |
| description | The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. |
| first_indexed | 2024-03-06T05:30:06Z |
| format | Article |
| id | um.eprints-12001 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:06Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-120012019-01-30T08:18:27Z http://eprints.um.edu.my/12001/ (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. Q Science (General) The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. International Union of Crystallography 2010 Article PeerReviewed Zhang, Kou-Lin and Diao, Guo-Wang and Ng, S.W. (2010) (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1421-U783. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Zhang, Kou-Lin Diao, Guo-Wang Ng, S.W. (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title | (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_full | (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_fullStr | (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_full_unstemmed | (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_short | (5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate |
| title_sort | 5 aminoisophthalato kappa n triaqua 1 10 phenanthroline kappa n 2 n cobalt ii trihydrate |
| topic | Q Science (General) |
| work_keys_str_mv | AT zhangkoulin 5aminoisophthalatokappantriaqua110phenanthrolinekappan2ncobaltiitrihydrate AT diaoguowang 5aminoisophthalatokappantriaqua110phenanthrolinekappan2ncobaltiitrihydrate AT ngsw 5aminoisophthalatokappantriaqua110phenanthrolinekappan2ncobaltiitrihydrate |