N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine
Two independent half-molecules, each being completed by inversion symmetry, comprise the asymmetric unit of the title compound, C14H16N2S2. The major difference between the molecules is found in the central C-C bond [the C-N-C-C torsion angles are 114.66 (18) and 128.94 (18)degrees in the two molecu...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720122240663552 |
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| author | Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. |
| author_facet | Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. |
| author_sort | Prasath, R. |
| collection | UM |
| description | Two independent half-molecules, each being completed by inversion symmetry, comprise the asymmetric unit of the title compound, C14H16N2S2. The major difference between the molecules is found in the central C-C bond [the C-N-C-C torsion angles are 114.66 (18) and 128.94 (18)degrees in the two molecules]. The thiophene and imine groups are almost co-planar in each case [S-C-C-N torsion angles = -6.9 (2) and -3.6 (2)degrees]. In the crystal, the molecules aggregate into supramolecular chains via C-H center dot center dot center dot pi interactions. |
| first_indexed | 2024-03-06T05:30:12Z |
| format | Article |
| id | um.eprints-12034 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:12Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-120342019-01-31T05:14:41Z http://eprints.um.edu.my/12034/ N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. Q Science (General) R Medicine Two independent half-molecules, each being completed by inversion symmetry, comprise the asymmetric unit of the title compound, C14H16N2S2. The major difference between the molecules is found in the central C-C bond [the C-N-C-C torsion angles are 114.66 (18) and 128.94 (18)degrees in the two molecules]. The thiophene and imine groups are almost co-planar in each case [S-C-C-N torsion angles = -6.9 (2) and -3.6 (2)degrees]. In the crystal, the molecules aggregate into supramolecular chains via C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Prasath, R. and Bhavana, P. and Ng, S.W. and Tiekink, E.R.T. (2010) N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine. Acta Crystallographica Section E: Structure Reports Online, 66 (11). O2884-U796. ISSN 1600-5368, |
| spellingShingle | Q Science (General) R Medicine Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine |
| title | N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine |
| title_full | N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine |
| title_fullStr | N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine |
| title_full_unstemmed | N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine |
| title_short | N,N `-Bis[(E)-(3-methyl-2-thienyl)methylidene]ethane-1,2-diamine |
| title_sort | n n bis e 3 methyl 2 thienyl methylidene ethane 1 2 diamine |
| topic | Q Science (General) R Medicine |
| work_keys_str_mv | AT prasathr nnbise3methyl2thienylmethylideneethane12diamine AT bhavanap nnbise3methyl2thienylmethylideneethane12diamine AT ngsw nnbise3methyl2thienylmethylideneethane12diamine AT tiekinkert nnbise3methyl2thienylmethylideneethane12diamine |