3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atom...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720122437795840 |
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| author | Reddy, B.P. Vijayakumar, V. Sarveswari, S. Ng, S.W. Tiekink, E.R.T. |
| author_facet | Reddy, B.P. Vijayakumar, V. Sarveswari, S. Ng, S.W. Tiekink, E.R.T. |
| author_sort | Reddy, B.P. |
| collection | UM |
| description | Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O-H center dot center dot center dot O hydrogen bonds. In the crystal, the presence of C-H center dot center dot center dot O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c. |
| first_indexed | 2024-03-06T05:30:12Z |
| format | Article |
| id | um.eprints-12035 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:12Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-120352019-01-31T05:17:13Z http://eprints.um.edu.my/12035/ 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one Reddy, B.P. Vijayakumar, V. Sarveswari, S. Ng, S.W. Tiekink, E.R.T. Q Science (General) Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O-H center dot center dot center dot O hydrogen bonds. In the crystal, the presence of C-H center dot center dot center dot O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c. International Union of Crystallography 2010 Article PeerReviewed Reddy, B.P. and Vijayakumar, V. and Sarveswari, S. and Ng, S.W. and Tiekink, E.R.T. (2010) 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 66 (11). O2806-U120. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Reddy, B.P. Vijayakumar, V. Sarveswari, S. Ng, S.W. Tiekink, E.R.T. 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_full | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_fullStr | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_full_unstemmed | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_short | 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one |
| title_sort | 3 hydroxy 2 2 hydroxy 4 4 dimethyl 6 oxocyclohex 1 en 1 yl 3 nitrop henyl methyl 5 5 dimethylcyclohex 2 en 1 one |
| topic | Q Science (General) |
| work_keys_str_mv | AT reddybp 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT vijayakumarv 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT sarveswaris 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT ngsw 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one AT tiekinkert 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one |