catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6...
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| Format: | Article |
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International Union of Crystallography
2010
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| author | Arman, H.D. Miller, T. Tiekink, E.R.T. |
| author_facet | Arman, H.D. Miller, T. Tiekink, E.R.T. |
| author_sort | Arman, H.D. |
| collection | UM |
| description | The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6 coordination geometry, which is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supramolecular chain along the c axis; these are consolidated in the crystal by C-H center dot center dot center dot F interactions. |
| first_indexed | 2024-03-06T05:30:35Z |
| format | Article |
| id | um.eprints-12188 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:35Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-121882019-01-31T01:10:26Z http://eprints.um.edu.my/12188/ catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] Arman, H.D. Miller, T. Tiekink, E.R.T. Q Science (General) The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6 coordination geometry, which is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supramolecular chain along the c axis; these are consolidated in the crystal by C-H center dot center dot center dot F interactions. International Union of Crystallography 2010 Article PeerReviewed Arman, H.D. and Miller, T. and Tiekink, E.R.T. (2010) catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1212-U419. ISSN 1600-5368, (In Press) |
| spellingShingle | Q Science (General) Arman, H.D. Miller, T. Tiekink, E.R.T. catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] |
| title | catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] |
| title_full | catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] |
| title_fullStr | catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] |
| title_full_unstemmed | catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] |
| title_short | catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] |
| title_sort | catena poly 2 pyridone kappa o silver i l mu 2 pyridone kappa o 2 o hexafluoridophosphate |
| topic | Q Science (General) |
| work_keys_str_mv | AT armanhd catenapoly2pyridonekappaosilverilmu2pyridonekappao2ohexafluoridophosphate AT millert catenapoly2pyridonekappaosilverilmu2pyridonekappao2ohexafluoridophosphate AT tiekinkert catenapoly2pyridonekappaosilverilmu2pyridonekappao2ohexafluoridophosphate |