[2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II)
In the molecule of the title compound, [FeCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe-II atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pa...
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| Format: | Article |
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International Union of Crystallography
2010
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| Summary: | In the molecule of the title compound, [FeCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe-II atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938 (11):0.062 (11) ratio. Intermolecular C-H center dot center dot center dot Cl hydrogen bonding occurs in the crystal structure. |
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