[2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II)
In the molecule of the title compound, [FeCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe-II atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pa...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720147872055296 |
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| author | Li, Xiao-Ping Zhao, Jian-She Ng, S.W. |
| author_facet | Li, Xiao-Ping Zhao, Jian-She Ng, S.W. |
| author_sort | Li, Xiao-Ping |
| collection | UM |
| description | In the molecule of the title compound, [FeCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe-II atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938 (11):0.062 (11) ratio. Intermolecular C-H center dot center dot center dot Cl hydrogen bonding occurs in the crystal structure. |
| first_indexed | 2024-03-06T05:30:36Z |
| format | Article |
| id | um.eprints-12194 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:36Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-121942019-01-31T04:38:30Z http://eprints.um.edu.my/12194/ [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) Li, Xiao-Ping Zhao, Jian-She Ng, S.W. Q Science (General) In the molecule of the title compound, [FeCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe-II atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938 (11):0.062 (11) ratio. Intermolecular C-H center dot center dot center dot Cl hydrogen bonding occurs in the crystal structure. International Union of Crystallography 2010 Article PeerReviewed Li, Xiao-Ping and Zhao, Jian-She and Ng, S.W. (2010) [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1299-U1195. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Li, Xiao-Ping Zhao, Jian-She Ng, S.W. [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) |
| title | [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) |
| title_full | [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) |
| title_fullStr | [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) |
| title_full_unstemmed | [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) |
| title_short | [2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridoiron(II) |
| title_sort | 2 6 bis 6 methylquinolin 2 yl pyridine kappa n 3 n n dichloridoiron ii |
| topic | Q Science (General) |
| work_keys_str_mv | AT lixiaoping 26bis6methylquinolin2ylpyridinekappan3nndichloridoironii AT zhaojianshe 26bis6methylquinolin2ylpyridinekappan3nndichloridoironii AT ngsw 26bis6methylquinolin2ylpyridinekappan3nndichloridoironii |