[2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-b...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720148265271296 |
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| author | Li, Xiao-Ping Zhao, Jian-She Ng, S.W. |
| author_facet | Li, Xiao-Ping Zhao, Jian-She Ng, S.W. |
| author_sort | Li, Xiao-Ping |
| collection | UM |
| description | The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu-II atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). |
| first_indexed | 2024-03-06T05:30:36Z |
| format | Article |
| id | um.eprints-12196 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:36Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-121962019-01-31T04:39:01Z http://eprints.um.edu.my/12196/ [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) Li, Xiao-Ping Zhao, Jian-She Ng, S.W. Q Science (General) The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu-II atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). International Union of Crystallography 2010 Article PeerReviewed Li, Xiao-Ping and Zhao, Jian-She and Ng, S.W. (2010) [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1297-U1175. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Li, Xiao-Ping Zhao, Jian-She Ng, S.W. [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) |
| title | [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) |
| title_full | [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) |
| title_fullStr | [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) |
| title_full_unstemmed | [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) |
| title_short | [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) |
| title_sort | 2 6 bis p tolyliminomethyl pyridine kappa n 3 n n dichloridocopper ii |
| topic | Q Science (General) |
| work_keys_str_mv | AT lixiaoping 26bisptolyliminomethylpyridinekappan3nndichloridocopperii AT zhaojianshe 26bisptolyliminomethylpyridinekappan3nndichloridocopperii AT ngsw 26bisptolyliminomethylpyridinekappan3nndichloridocopperii |