Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)]
The title compound, [AgCd(NCS)(3)(C22H17N3)](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2-'' terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the A...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946365068083200 |
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| author | Li, Yu-Yang Wei, Zhen-Hong Ng, S.W. |
| author_facet | Li, Yu-Yang Wei, Zhen-Hong Ng, S.W. |
| author_sort | Li, Yu-Yang |
| collection | UM |
| description | The title compound, [AgCd(NCS)(3)(C22H17N3)](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2-'' terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordinated by the four S atoms of four thiocyanate ions in a distorted tetrahedral geometry. Of the three thiocyanate ions, one functions in a mu 2-bridging mode and two in a mu 3-bridging mode. The ribbon coordination polymer propagates along the a-axis. |
| first_indexed | 2024-03-06T05:30:36Z |
| format | Article |
| id | um.eprints-12197 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:36Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-121972019-01-31T04:39:16Z http://eprints.um.edu.my/12197/ Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] Li, Yu-Yang Wei, Zhen-Hong Ng, S.W. Q Science (General) The title compound, [AgCd(NCS)(3)(C22H17N3)](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2-'' terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordinated by the four S atoms of four thiocyanate ions in a distorted tetrahedral geometry. Of the three thiocyanate ions, one functions in a mu 2-bridging mode and two in a mu 3-bridging mode. The ribbon coordination polymer propagates along the a-axis. International Union of Crystallography 2010 Article PeerReviewed Li, Yu-Yang and Wei, Zhen-Hong and Ng, S.W. (2010) Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1313-U1326. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Li, Yu-Yang Wei, Zhen-Hong Ng, S.W. Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] |
| title | Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] |
| title_full | Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] |
| title_fullStr | Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] |
| title_full_unstemmed | Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] |
| title_short | Poly[bis(mu(3)-thiocyanato-kappa N-3:S:S `)(mu(2)-thiocyanato-kappa N-2/S)(4 `-p-tolyl-2,2 `/6 `,2 `'-terpyridine-kappa N-3,N `,N `')cadmium(II)silver(I)] |
| title_sort | poly bis mu 3 thiocyanato kappa n 3 s s mu 2 thiocyanato kappa n 2 s 4 p tolyl 2 2 6 2 terpyridine kappa n 3 n n cadmium ii silver i |
| topic | Q Science (General) |
| work_keys_str_mv | AT liyuyang polybismu3thiocyanatokappan3ssmu2thiocyanatokappan2s4ptolyl2262terpyridinekappan3nncadmiumiisilveri AT weizhenhong polybismu3thiocyanatokappan3ssmu2thiocyanatokappan2s4ptolyl2262terpyridinekappan3nncadmiumiisilveri AT ngsw polybismu3thiocyanatokappan3ssmu2thiocyanatokappan2s4ptolyl2262terpyridinekappan3nncadmiumiisilveri |