Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate
The title compound, [ZnBr(C9H6NO)(C9H7NO)]center dot CH3OH, has its metal atom N,O-chelated by a neutral and a deprotonated 8-hydroxyquinoline ligand. The hydroxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alkoxy O atom of the monoanionic ligand is a hydrogen-...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: |
| _version_ | 1825720148855619584 |
|---|---|
| author | Najafi, E. Amini, M.M. Ng, S.W. |
| author_facet | Najafi, E. Amini, M.M. Ng, S.W. |
| author_sort | Najafi, E. |
| collection | UM |
| description | The title compound, [ZnBr(C9H6NO)(C9H7NO)]center dot CH3OH, has its metal atom N,O-chelated by a neutral and a deprotonated 8-hydroxyquinoline ligand. The hydroxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alkoxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent molecules are linked by these two hydrogen bonds, generating a chain running along the a axis. |
| first_indexed | 2024-03-06T05:30:37Z |
| format | Article |
| id | um.eprints-12199 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:37Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-121992019-01-31T05:06:38Z http://eprints.um.edu.my/12199/ Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate Najafi, E. Amini, M.M. Ng, S.W. Q Science (General) The title compound, [ZnBr(C9H6NO)(C9H7NO)]center dot CH3OH, has its metal atom N,O-chelated by a neutral and a deprotonated 8-hydroxyquinoline ligand. The hydroxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alkoxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent molecules are linked by these two hydrogen bonds, generating a chain running along the a axis. International Union of Crystallography 2010 Article PeerReviewed Najafi, E. and Amini, M.M. and Ng, S.W. (2010) Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1278-U1024. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Najafi, E. Amini, M.M. Ng, S.W. Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title | Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_full | Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_fullStr | Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_full_unstemmed | Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_short | Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_sort | bromido quinolin 8 ol kappa n 2 o quinolin 8 olato kappa n 2 o zinc ii methanol monosolvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT najafie bromidoquinolin8olkappan2oquinolin8olatokappan2ozinciimethanolmonosolvate AT aminimm bromidoquinolin8olkappan2oquinolin8olatokappan2ozinciimethanolmonosolvate AT ngsw bromidoquinolin8olkappan2oquinolin8olatokappan2ozinciimethanolmonosolvate |