2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate

In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anio...

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Main Authors: Ou, Guang-Chuan, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
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author Ou, Guang-Chuan
Ng, S.W.
author_facet Ou, Guang-Chuan
Ng, S.W.
author_sort Ou, Guang-Chuan
collection UM
description In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio.
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spelling um.eprints-122022019-01-31T05:10:44Z http://eprints.um.edu.my/12202/ 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate Ou, Guang-Chuan Ng, S.W. Q Science (General) In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio. International Union of Crystallography 2010 Article PeerReviewed Ou, Guang-Chuan and Ng, S.W. (2010) 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1295-U1167. ISSN 1600-5368,
spellingShingle Q Science (General)
Ou, Guang-Chuan
Ng, S.W.
2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
title 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
title_full 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
title_fullStr 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
title_full_unstemmed 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
title_short 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
title_sort 2 aminobenzoato kappa o 2 o rac 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane kappa n 4 n n n nickel ii perchlorate monohydrate
topic Q Science (General)
work_keys_str_mv AT ouguangchuan 2aminobenzoatokappao2orac557121214hexamethyl14811tetraazacyclotetradecanekappan4nnnnickeliiperchloratemonohydrate
AT ngsw 2aminobenzoatokappao2orac557121214hexamethyl14811tetraazacyclotetradecanekappan4nnnnickeliiperchloratemonohydrate