2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate
In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anio...
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International Union of Crystallography
2010
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author | Ou, Guang-Chuan Ng, S.W. |
author_facet | Ou, Guang-Chuan Ng, S.W. |
author_sort | Ou, Guang-Chuan |
collection | UM |
description | In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio. |
first_indexed | 2024-03-06T05:30:37Z |
format | Article |
id | um.eprints-12202 |
institution | Universiti Malaya |
last_indexed | 2024-03-06T05:30:37Z |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-122022019-01-31T05:10:44Z http://eprints.um.edu.my/12202/ 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate Ou, Guang-Chuan Ng, S.W. Q Science (General) In the title salt, [Ni(C7H6NO2)(C16H36N4)]ClO4 center dot H2O, the Ni-II cation is O,O'-chelated by the benzoate anion andN,N',N `',N'''-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio. International Union of Crystallography 2010 Article PeerReviewed Ou, Guang-Chuan and Ng, S.W. (2010) 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1295-U1167. ISSN 1600-5368, |
spellingShingle | Q Science (General) Ou, Guang-Chuan Ng, S.W. 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate |
title | 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate |
title_full | 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate |
title_fullStr | 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate |
title_full_unstemmed | 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate |
title_short | 2-Aminobenzoato-kappa O-2,O `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate monohydrate |
title_sort | 2 aminobenzoato kappa o 2 o rac 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane kappa n 4 n n n nickel ii perchlorate monohydrate |
topic | Q Science (General) |
work_keys_str_mv | AT ouguangchuan 2aminobenzoatokappao2orac557121214hexamethyl14811tetraazacyclotetradecanekappan4nnnnickeliiperchloratemonohydrate AT ngsw 2aminobenzoatokappao2orac557121214hexamethyl14811tetraazacyclotetradecanekappan4nnnnickeliiperchloratemonohydrate |