Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one c...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720149816115200 |
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| author | Su, M. Huang, Zhan-Dong Sun, H. Yang, G. Ng, S.W. |
| author_facet | Su, M. Huang, Zhan-Dong Sun, H. Yang, G. Ng, S.W. |
| author_sort | Su, M. |
| collection | UM |
| description | In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one carboxylate group chelating to a metal atom whereas the other bridges two metal atoms in a mu(3)-bridging mode. Both metal atoms show an octahedral coordination. The polymer adopts a layer motif, with the lattice dimethylformamide molecules occupying the space between adjacent layers. |
| first_indexed | 2024-03-06T05:30:38Z |
| format | Article |
| id | um.eprints-12204 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:30:38Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-122042019-01-30T09:16:29Z http://eprints.um.edu.my/12204/ Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] Su, M. Huang, Zhan-Dong Sun, H. Yang, G. Ng, S.W. Q Science (General) In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one carboxylate group chelating to a metal atom whereas the other bridges two metal atoms in a mu(3)-bridging mode. Both metal atoms show an octahedral coordination. The polymer adopts a layer motif, with the lattice dimethylformamide molecules occupying the space between adjacent layers. International Union of Crystallography 2010 Article PeerReviewed Su, M. and Huang, Zhan-Dong and Sun, H. and Yang, G. and Ng, S.W. (2010) Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1220-U493. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Su, M. Huang, Zhan-Dong Sun, H. Yang, G. Ng, S.W. Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] |
| title | Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] |
| title_full | Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] |
| title_fullStr | Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] |
| title_full_unstemmed | Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] |
| title_short | Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] |
| title_sort | poly tris n n dimethylformamide mu 4 5 nitroisophthalato mu 3 5 nitroisophthalato dicobalt ii n n dimethylformamide monosolvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT sum polytrisnndimethylformamidemu45nitroisophthalatomu35nitroisophthalatodicobaltiinndimethylformamidemonosolvate AT huangzhandong polytrisnndimethylformamidemu45nitroisophthalatomu35nitroisophthalatodicobaltiinndimethylformamidemonosolvate AT sunh polytrisnndimethylformamidemu45nitroisophthalatomu35nitroisophthalatodicobaltiinndimethylformamidemonosolvate AT yangg polytrisnndimethylformamidemu45nitroisophthalatomu35nitroisophthalatodicobaltiinndimethylformamidemonosolvate AT ngsw polytrisnndimethylformamidemu45nitroisophthalatomu35nitroisophthalatodicobaltiinndimethylformamidemonosolvate |