(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towa...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720178981208064 |
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| author | Awang, N. Baba, I. Yamin, B.M. Ng, S.W. Tiekink, E.R.T. |
| author_facet | Awang, N. Baba, I. Yamin, B.M. Ng, S.W. Tiekink, E.R.T. |
| author_sort | Awang, N. |
| collection | UM |
| description | The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions. |
| first_indexed | 2024-03-06T05:31:05Z |
| format | Article |
| id | um.eprints-12409 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:05Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-124092019-01-31T01:13:57Z http://eprints.um.edu.my/12409/ (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) Awang, N. Baba, I. Yamin, B.M. Ng, S.W. Tiekink, E.R.T. Q Science (General) The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Awang, N. and Baba, I. and Yamin, B.M. and Ng, S.W. and Tiekink, E.R.T. (2010) (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1144-U948. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Awang, N. Baba, I. Yamin, B.M. Ng, S.W. Tiekink, E.R.T. (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) |
| title | (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) |
| title_full | (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) |
| title_fullStr | (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) |
| title_full_unstemmed | (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) |
| title_short | (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) |
| title_sort | n sec butyl n n propyldithiocarbamato kappa s 2 s triphenyltin iv |
| topic | Q Science (General) |
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