{2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydr...
| Những tác giả chính: | , , , |
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| Định dạng: | Bài viết |
| Được phát hành: |
International Union of Crystallography
2010
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| Những chủ đề: |
| Tóm tắt: | The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis. |
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