{2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydr...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720180742815744 |
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| author | Shawish, H.B. Tan, K.W. Maah, Mohd Jamil Ng, S.W. |
| author_facet | Shawish, H.B. Tan, K.W. Maah, Mohd Jamil Ng, S.W. |
| author_sort | Shawish, H.B. |
| collection | UM |
| description | The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis. |
| first_indexed | 2024-03-06T05:31:06Z |
| format | Article |
| id | um.eprints-12418 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:06Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-124182019-01-30T09:13:55Z http://eprints.um.edu.my/12418/ {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride Shawish, H.B. Tan, K.W. Maah, Mohd Jamil Ng, S.W. Q Science (General) The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis. International Union of Crystallography 2010 Article PeerReviewed Shawish, H.B. and Tan, K.W. and Maah, Mohd Jamil and Ng, S.W. (2010) {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1074-U374. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Shawish, H.B. Tan, K.W. Maah, Mohd Jamil Ng, S.W. {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride |
| title | {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride |
| title_full | {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride |
| title_fullStr | {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride |
| title_full_unstemmed | {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride |
| title_short | {2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride |
| title_sort | 2 2 carbamothiolylhydrazin 1 ylidene kappa n 2 1 s methyl 6 hydroxyphenolato kappa o 1 triphenylphosphine kappa p nickel ii chloride |
| topic | Q Science (General) |
| work_keys_str_mv | AT shawishhb 22carbamothiolylhydrazin1ylidenekappan21smethyl6hydroxyphenolatokappao1triphenylphosphinekappapnickeliichloride AT tankw 22carbamothiolylhydrazin1ylidenekappan21smethyl6hydroxyphenolatokappao1triphenylphosphinekappapnickeliichloride AT maahmohdjamil 22carbamothiolylhydrazin1ylidenekappan21smethyl6hydroxyphenolatokappao1triphenylphosphinekappapnickeliichloride AT ngsw 22carbamothiolylhydrazin1ylidenekappan21smethyl6hydroxyphenolatokappao1triphenylphosphinekappapnickeliichloride |