(Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV)
The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol molecule and carboxylate group occupy the apical sites. In the crystal, adjacent molecules are...
Main Authors: | , , , |
---|---|
Format: | Article |
Published: |
International Union of Crystallography
2010
|
Subjects: |
_version_ | 1796946400192233472 |
---|---|
author | Yip, F.W. Teoh, S.G. Yamin, B.M. Ng, S.W. |
author_facet | Yip, F.W. Teoh, S.G. Yamin, B.M. Ng, S.W. |
author_sort | Yip, F.W. |
collection | UM |
description | The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol molecule and carboxylate group occupy the apical sites. In the crystal, adjacent molecules are linked by intermolecular O-H center dot center dot center dot O interactions, generating a helical hydrogen-bonded chain running along the b axis. |
first_indexed | 2024-03-06T05:31:07Z |
format | Article |
id | um.eprints-12419 |
institution | Universiti Malaya |
last_indexed | 2024-03-06T05:31:07Z |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-124192019-01-30T08:20:52Z http://eprints.um.edu.my/12419/ (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) Yip, F.W. Teoh, S.G. Yamin, B.M. Ng, S.W. Q Science (General) The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol molecule and carboxylate group occupy the apical sites. In the crystal, adjacent molecules are linked by intermolecular O-H center dot center dot center dot O interactions, generating a helical hydrogen-bonded chain running along the b axis. International Union of Crystallography 2010 Article PeerReviewed Yip, F.W. and Teoh, S.G. and Yamin, B.M. and Ng, S.W. (2010) (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1164-U1125. ISSN 1600-5368, |
spellingShingle | Q Science (General) Yip, F.W. Teoh, S.G. Yamin, B.M. Ng, S.W. (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) |
title | (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) |
title_full | (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) |
title_fullStr | (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) |
title_full_unstemmed | (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) |
title_short | (Methanol-kappa O)(2-methyl-3-nitrobenzoato-kappa O)triphenyltin(IV) |
title_sort | methanol kappa o 2 methyl 3 nitrobenzoato kappa o triphenyltin iv |
topic | Q Science (General) |
work_keys_str_mv | AT yipfw methanolkappao2methyl3nitrobenzoatokappaotriphenyltiniv AT teohsg methanolkappao2methyl3nitrobenzoatokappaotriphenyltiniv AT yaminbm methanolkappao2methyl3nitrobenzoatokappaotriphenyltiniv AT ngsw methanolkappao2methyl3nitrobenzoatokappaotriphenyltiniv |