{4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV)
Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)(2)(C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: |
| _version_ | 1825720196766105600 |
|---|---|
| author | Abu Affan, M. Sam, N.B. Ahmad, F.B. Tiekink, E.R.T. |
| author_facet | Abu Affan, M. Sam, N.B. Ahmad, F.B. Tiekink, E.R.T. |
| author_sort | Abu Affan, M. |
| collection | UM |
| description | Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)(2)(C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. Zigzag chains running along the a axis mediated by O-H center dot center dot center dot N hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C-H center dot center dot center dot N and pi-pi [centroid-centroid distances = 3.658 (2) and 3.6740 (18) angstrom] interactions. The layers are connected along the c axis via C-H center dot center dot center dot O interactions. |
| first_indexed | 2024-03-06T05:31:21Z |
| format | Article |
| id | um.eprints-12528 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:21Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-125282019-01-31T01:39:15Z http://eprints.um.edu.my/12528/ {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) Abu Affan, M. Sam, N.B. Ahmad, F.B. Tiekink, E.R.T. Q Science (General) Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)(2)(C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. Zigzag chains running along the a axis mediated by O-H center dot center dot center dot N hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C-H center dot center dot center dot N and pi-pi [centroid-centroid distances = 3.658 (2) and 3.6740 (18) angstrom] interactions. The layers are connected along the c axis via C-H center dot center dot center dot O interactions. International Union of Crystallography 2010 Article PeerReviewed Abu Affan, M. and Sam, N.B. and Ahmad, F.B. and Tiekink, E.R.T. (2010) {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M924-U596. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Abu Affan, M. Sam, N.B. Ahmad, F.B. Tiekink, E.R.T. {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) |
| title | {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) |
| title_full | {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) |
| title_fullStr | {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) |
| title_full_unstemmed | {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) |
| title_short | {4-Hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylidene]benzohydrazidato-kappa(2) N `,O}dimethyltin(IV) |
| title_sort | 4 hydroxy n 2 oxido 1 naphthyl kappa o methylidene benzohydrazidato kappa 2 n o dimethyltin iv |
| topic | Q Science (General) |
| work_keys_str_mv | AT abuaffanm 4hydroxyn2oxido1naphthylkappaomethylidenebenzohydrazidatokappa2nodimethyltiniv AT samnb 4hydroxyn2oxido1naphthylkappaomethylidenebenzohydrazidatokappa2nodimethyltiniv AT ahmadfb 4hydroxyn2oxido1naphthylkappaomethylidenebenzohydrazidatokappa2nodimethyltiniv AT tiekinkert 4hydroxyn2oxido1naphthylkappaomethylidenebenzohydrazidatokappa2nodimethyltiniv |