catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2]
In the title polymeric complex, [Sn(C6H5)(3)(C14H16NO3)] (n) , adjacent triphenyltin cations are bridged by the N-cyclohexylphthalamate anion through the carboxylate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated...
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International Union of Crystallography
2010
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author | Imtiaz, Ud-Din Raqiqt, Ul-Rasool Bhatti, M.H. Ng, S.W. |
author_facet | Imtiaz, Ud-Din Raqiqt, Ul-Rasool Bhatti, M.H. Ng, S.W. |
author_sort | Imtiaz, Ud-Din |
collection | UM |
description | In the title polymeric complex, [Sn(C6H5)(3)(C14H16NO3)] (n) , adjacent triphenyltin cations are bridged by the N-cyclohexylphthalamate anion through the carboxylate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxylate O atom. The geometry at the five-coordinate Sn atom is trans-C3SnO2 trigonal-bipyramidal. |
first_indexed | 2024-03-06T05:31:22Z |
format | Article |
id | um.eprints-12531 |
institution | Universiti Malaya |
last_indexed | 2024-03-06T05:31:22Z |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-125312019-01-31T04:17:22Z http://eprints.um.edu.my/12531/ catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] Imtiaz, Ud-Din Raqiqt, Ul-Rasool Bhatti, M.H. Ng, S.W. Q Science (General) In the title polymeric complex, [Sn(C6H5)(3)(C14H16NO3)] (n) , adjacent triphenyltin cations are bridged by the N-cyclohexylphthalamate anion through the carboxylate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxylate O atom. The geometry at the five-coordinate Sn atom is trans-C3SnO2 trigonal-bipyramidal. International Union of Crystallography 2010 Article PeerReviewed Imtiaz, Ud-Din and Raqiqt, Ul-Rasool and Bhatti, M.H. and Ng, S.W. (2010) catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M931-U671. ISSN 1600-5368, |
spellingShingle | Q Science (General) Imtiaz, Ud-Din Raqiqt, Ul-Rasool Bhatti, M.H. Ng, S.W. catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] |
title | catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] |
title_full | catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] |
title_fullStr | catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] |
title_full_unstemmed | catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] |
title_short | catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2] |
title_sort | catena poly triphenyltin iv mu 2 cyclohexylaminocarbonyl benzoat o kappa 2 o 1 o 2 |
topic | Q Science (General) |
work_keys_str_mv | AT imtiazuddin catenapolytriphenyltinivmu2cyclohexylaminocarbonylbenzoatokappa2o1o2 AT raqiqtulrasool catenapolytriphenyltinivmu2cyclohexylaminocarbonylbenzoatokappa2o1o2 AT bhattimh catenapolytriphenyltinivmu2cyclohexylaminocarbonylbenzoatokappa2o1o2 AT ngsw catenapolytriphenyltinivmu2cyclohexylaminocarbonylbenzoatokappa2o1o2 |