Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)]
Two nicotinate binding modes are observed in the dinuclear title compound, [Sn-2(C7H6Br)(4)(C6H4NO2)(4)(H2O)(2)]: in the first, a terminal O,O'-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two ca...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720197766447104 |
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| author | Keng, C.T. Lo, K.M. Ng, S.W. |
| author_facet | Keng, C.T. Lo, K.M. Ng, S.W. |
| author_sort | Keng, C.T. |
| collection | UM |
| description | Two nicotinate binding modes are observed in the dinuclear title compound, [Sn-2(C7H6Br)(4)(C6H4NO2)(4)(H2O)(2)]: in the first, a terminal O,O'-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two cations. The two Sn atoms exist in trans-C2SnNO4 pentagonal-bipyramidal geometries. Adjacent dinuclear units are linked by O-H...N hydrogen bonds, generating a linear chain, which propagates in the b-axis direction. O-H...O interactions are also observed. |
| first_indexed | 2024-03-06T05:31:22Z |
| format | Article |
| id | um.eprints-12533 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:22Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-125332019-01-31T04:30:12Z http://eprints.um.edu.my/12533/ Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] Keng, C.T. Lo, K.M. Ng, S.W. Q Science (General) Two nicotinate binding modes are observed in the dinuclear title compound, [Sn-2(C7H6Br)(4)(C6H4NO2)(4)(H2O)(2)]: in the first, a terminal O,O'-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two cations. The two Sn atoms exist in trans-C2SnNO4 pentagonal-bipyramidal geometries. Adjacent dinuclear units are linked by O-H...N hydrogen bonds, generating a linear chain, which propagates in the b-axis direction. O-H...O interactions are also observed. International Union of Crystallography 2010 Article PeerReviewed Keng, C.T. and Lo, K.M. and Ng, S.W. (2010) Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M1008-U1378. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Keng, C.T. Lo, K.M. Ng, S.W. Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] |
| title | Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] |
| title_full | Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] |
| title_fullStr | Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] |
| title_full_unstemmed | Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] |
| title_short | Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)] |
| title_sort | di mu nicotinato kappa n 2 o kappa o 2 n bis aquabis 4 bromobenzyl nicotinato kappa o 2 o tin iv |
| topic | Q Science (General) |
| work_keys_str_mv | AT kengct dimunicotinatokappan2okappao2nbisaquabis4bromobenzylnicotinatokappao2otiniv AT lokm dimunicotinatokappan2okappao2nbisaquabis4bromobenzylnicotinatokappao2otiniv AT ngsw dimunicotinatokappan2okappao2nbisaquabis4bromobenzylnicotinatokappao2otiniv |