(Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium
The K atom in the title complex, [K(C(10)H(6)NO(2))(C(10)H(7)NO(2))(3)], lies on a twofold rotation axis that relates one N,O-chelating quinoline-2-carboxylic acid to the other; their N and O atoms are cis to each other in the distorted octahedral coordination geometry. The K atom is also coordinate...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720198570704896 |
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| author | Ng, S.W. |
| author_facet | Ng, S.W. |
| author_sort | Ng, S.W. |
| collection | UM |
| description | The K atom in the title complex, [K(C(10)H(6)NO(2))(C(10)H(7)NO(2))(3)], lies on a twofold rotation axis that relates one N,O-chelating quinoline-2-carboxylic acid to the other; their N and O atoms are cis to each other in the distorted octahedral coordination geometry. The K atom is also coordinated by another monodentate quinoline-2-carboxylic acid; the acid is disordered with respect to a monodentate quinoline-2-carboxylate anion; the acid and anion are linked by an O-H...O hydrogen bond. An O-H...N hydrogen bond links adjacent molecules into a linear chain structure along the a axis. |
| first_indexed | 2024-03-06T05:31:23Z |
| format | Article |
| id | um.eprints-12537 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:23Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-125372019-01-31T05:10:07Z http://eprints.um.edu.my/12537/ (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium Ng, S.W. QD Chemistry The K atom in the title complex, [K(C(10)H(6)NO(2))(C(10)H(7)NO(2))(3)], lies on a twofold rotation axis that relates one N,O-chelating quinoline-2-carboxylic acid to the other; their N and O atoms are cis to each other in the distorted octahedral coordination geometry. The K atom is also coordinated by another monodentate quinoline-2-carboxylic acid; the acid is disordered with respect to a monodentate quinoline-2-carboxylate anion; the acid and anion are linked by an O-H...O hydrogen bond. An O-H...N hydrogen bond links adjacent molecules into a linear chain structure along the a axis. International Union of Crystallography 2010 Article PeerReviewed Ng, S.W. (2010) (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M948-U836. ISSN 1600-5368, |
| spellingShingle | QD Chemistry Ng, S.W. (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium |
| title | (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium |
| title_full | (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium |
| title_fullStr | (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium |
| title_full_unstemmed | (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium |
| title_short | (Quinoline-2-carboxylato-kappa O)(quinoline-2-carboxylic acid-kappa O)bis(quinoline-2-carboxylic acid-kappa 2 N,O)potassium |
| title_sort | quinoline 2 carboxylato kappa o quinoline 2 carboxylic acid kappa o bis quinoline 2 carboxylic acid kappa 2 n o potassium |
| topic | QD Chemistry |
| work_keys_str_mv | AT ngsw quinoline2carboxylatokappaoquinoline2carboxylicacidkappaobisquinoline2carboxylicacidkappa2nopotassium |