Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720199556366336 |
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| author | Tajidi, N.S.A. Abdullah, N. Arifin, Z. Tan, K.W. Ng, S.W. |
| author_facet | Tajidi, N.S.A. Abdullah, N. Arifin, Z. Tan, K.W. Ng, S.W. |
| author_sort | Tajidi, N.S.A. |
| collection | UM |
| description | The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001) |
| first_indexed | 2024-03-06T05:31:24Z |
| format | Article |
| id | um.eprints-12542 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:24Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-125422019-01-30T09:03:51Z http://eprints.um.edu.my/12542/ Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate Tajidi, N.S.A. Abdullah, N. Arifin, Z. Tan, K.W. Ng, S.W. QD Chemistry The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001) International Union of Crystallography 2010 Article PeerReviewed Tajidi, N.S.A. and Abdullah, N. and Arifin, Z. and Tan, K.W. and Ng, S.W. (2010) Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M889-U302. ISSN 1600-5368, |
| spellingShingle | QD Chemistry Tajidi, N.S.A. Abdullah, N. Arifin, Z. Tan, K.W. Ng, S.W. Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate |
| title | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate |
| title_full | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate |
| title_fullStr | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate |
| title_full_unstemmed | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate |
| title_short | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate |
| title_sort | diaqua 1 4 8 11 tetraazacyclotetradecane kappa 4 n 1 n 4 n 8 n 11 copper ii bis 2 3 4 5 6 pentafluorobenzoate dihydrate |
| topic | QD Chemistry |
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