Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]

The SnIV atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octahedral coordination [C-Sn-C = 157.83 (8)degrees]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-re...

Full description

Bibliographic Details
Main Authors: Vafaee, M., Amini, M.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
_version_ 1825720199935950848
author Vafaee, M.
Amini, M.M.
Ng, S.W.
author_facet Vafaee, M.
Amini, M.M.
Ng, S.W.
author_sort Vafaee, M.
collection UM
description The SnIV atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octahedral coordination [C-Sn-C = 157.83 (8)degrees]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak intermolecular C-H...Cl hydrogen bonding links the molecules, forming supramolecular chains running along [100].
first_indexed 2024-03-06T05:31:24Z
format Article
id um.eprints-12544
institution Universiti Malaya
last_indexed 2024-03-06T05:31:24Z
publishDate 2010
publisher International Union of Crystallography
record_format dspace
spelling um.eprints-125442019-01-30T08:32:07Z http://eprints.um.edu.my/12544/ Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)] Vafaee, M. Amini, M.M. Ng, S.W. QD Chemistry The SnIV atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octahedral coordination [C-Sn-C = 157.83 (8)degrees]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak intermolecular C-H...Cl hydrogen bonding links the molecules, forming supramolecular chains running along [100]. International Union of Crystallography 2010 Article PeerReviewed Vafaee, M. and Amini, M.M. and Ng, S.W. (2010) Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M964-U947. ISSN 1600-5368,
spellingShingle QD Chemistry
Vafaee, M.
Amini, M.M.
Ng, S.W.
Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]
title Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]
title_full Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]
title_fullStr Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]
title_full_unstemmed Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]
title_short Bis(mu-quinolin-8-olato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[chloridomethylphenyltin(IV)]
title_sort bis mu quinolin 8 olato kappa 3 n o o kappa 3 o n o bis chloridomethylphenyltin iv
topic QD Chemistry
work_keys_str_mv AT vafaeem bismuquinolin8olatokappa3nookappa3onobischloridomethylphenyltiniv
AT aminimm bismuquinolin8olatokappa3nookappa3onobischloridomethylphenyltiniv
AT ngsw bismuquinolin8olatokappa3nookappa3onobischloridomethylphenyltiniv