Kingianin A: A new natural pentacyclic compound from Endiandra kingiana

A new natural pentacyclic compound, named kingianin A, was isolated as a racemic mixture from the barks of Endiandra kingiana (Lauraceae). Its structure was elucidated by comprehensive analysis of NMR spectroscopic data, X-ray crystallography, and ECD calculations. The pentacyclic skeleton may be fo...

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मुख्य लेखकों: Leverrier, A., Dau, M.E.T.H., Retailleau, P., Awang, Khalijah, Gueritte, F., Litaudon, M.
स्वरूप: लेख
प्रकाशित: American Chemical Society 2010
विषय:
विवरण
सारांश:A new natural pentacyclic compound, named kingianin A, was isolated as a racemic mixture from the barks of Endiandra kingiana (Lauraceae). Its structure was elucidated by comprehensive analysis of NMR spectroscopic data, X-ray crystallography, and ECD calculations. The pentacyclic skeleton may be formed by a Diels-Alder reaction between two monomers having a bicyclo[4.2.0]octadiene backbone formed by a stereospecific electrocyclization of a linear compound of polyketide origin.