N-(3,4-Dimethylphenyl)benzenesulfonamide
The structure of the title compound, C(14)H(15)NO(2)S, shows the sulfonamide N atom to be approximately perpendicular to the plane through the S-bound benzene ring [the N-S-C-C torsion angle is -87.4 (3)degrees] and to lie to the opposide side of this ring to the two sulfonamide O atoms. The N-bound...
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| Format: | Article |
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International Union of Crystallography
2010
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| author | John, P. Sharif, S. Khan, I.U. Khizar, S. Tiekink, E.R.T. |
| author_facet | John, P. Sharif, S. Khan, I.U. Khizar, S. Tiekink, E.R.T. |
| author_sort | John, P. |
| collection | UM |
| description | The structure of the title compound, C(14)H(15)NO(2)S, shows the sulfonamide N atom to be approximately perpendicular to the plane through the S-bound benzene ring [the N-S-C-C torsion angle is -87.4 (3)degrees] and to lie to the opposide side of this ring to the two sulfonamide O atoms. The N-bound benzene ring is splayed out with respect to the rest of the molecule so that overall, the molecule adopts a twisted conformation. The dihedral angle between the two benzene rings is 64.5 (3)degrees. In the crystal, supramolecular chains aligned along the b axis are formed via N-H...O hydrogen bonds. |
| first_indexed | 2024-03-06T05:31:30Z |
| format | Article |
| id | um.eprints-12579 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:30Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-125792019-01-31T04:27:38Z http://eprints.um.edu.my/12579/ N-(3,4-Dimethylphenyl)benzenesulfonamide John, P. Sharif, S. Khan, I.U. Khizar, S. Tiekink, E.R.T. Q Science (General) The structure of the title compound, C(14)H(15)NO(2)S, shows the sulfonamide N atom to be approximately perpendicular to the plane through the S-bound benzene ring [the N-S-C-C torsion angle is -87.4 (3)degrees] and to lie to the opposide side of this ring to the two sulfonamide O atoms. The N-bound benzene ring is splayed out with respect to the rest of the molecule so that overall, the molecule adopts a twisted conformation. The dihedral angle between the two benzene rings is 64.5 (3)degrees. In the crystal, supramolecular chains aligned along the b axis are formed via N-H...O hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed John, P. and Sharif, S. and Khan, I.U. and Khizar, S. and Tiekink, E.R.T. (2010) N-(3,4-Dimethylphenyl)benzenesulfonamide. Acta Crystallographica Section E: Structure Reports Online, 66 (8). O1983-U883. ISSN 1600-5368, |
| spellingShingle | Q Science (General) John, P. Sharif, S. Khan, I.U. Khizar, S. Tiekink, E.R.T. N-(3,4-Dimethylphenyl)benzenesulfonamide |
| title | N-(3,4-Dimethylphenyl)benzenesulfonamide |
| title_full | N-(3,4-Dimethylphenyl)benzenesulfonamide |
| title_fullStr | N-(3,4-Dimethylphenyl)benzenesulfonamide |
| title_full_unstemmed | N-(3,4-Dimethylphenyl)benzenesulfonamide |
| title_short | N-(3,4-Dimethylphenyl)benzenesulfonamide |
| title_sort | n 3 4 dimethylphenyl benzenesulfonamide |
| topic | Q Science (General) |
| work_keys_str_mv | AT johnp n34dimethylphenylbenzenesulfonamide AT sharifs n34dimethylphenylbenzenesulfonamide AT khaniu n34dimethylphenylbenzenesulfonamide AT khizars n34dimethylphenylbenzenesulfonamide AT tiekinkert n34dimethylphenylbenzenesulfonamide |