tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate
In the molecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(aryl)-C-C(aryl) angle to 111.5 (1)degrees. The four-atom -O-CH(2)-C(=O)-O- linkage between the aromatic ring and the tert-butyl group assumes a (...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: |
| _version_ | 1825720224560709632 |
|---|---|
| author | Ali, Q. Yousuf, S. Shah, M.R. Ng, S.W. |
| author_facet | Ali, Q. Yousuf, S. Shah, M.R. Ng, S.W. |
| author_sort | Ali, Q. |
| collection | UM |
| description | In the molecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(aryl)-C-C(aryl) angle to 111.5 (1)degrees. The four-atom -O-CH(2)-C(=O)-O- linkage between the aromatic ring and the tert-butyl group assumes a (-)anti-periplanar conformation for one substituent and a (-)syn-periplanar conformation for the other substituent; the O-C-C-O torsion angles are -173.7 (2) and -10.2 (3)degrees. |
| first_indexed | 2024-03-06T05:31:47Z |
| format | Article |
| id | um.eprints-12712 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:31:47Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-127122019-01-31T01:25:36Z http://eprints.um.edu.my/12712/ tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate Ali, Q. Yousuf, S. Shah, M.R. Ng, S.W. QD Chemistry In the molecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(aryl)-C-C(aryl) angle to 111.5 (1)degrees. The four-atom -O-CH(2)-C(=O)-O- linkage between the aromatic ring and the tert-butyl group assumes a (-)anti-periplanar conformation for one substituent and a (-)syn-periplanar conformation for the other substituent; the O-C-C-O torsion angles are -173.7 (2) and -10.2 (3)degrees. International Union of Crystallography 2010 Article PeerReviewed Ali, Q. and Yousuf, S. and Shah, M.R. and Ng, S.W. (2010) tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate. Acta Crystallographica Section E: Structure Reports Online, 66 (7). O1750-U111. ISSN 1600-5368, |
| spellingShingle | QD Chemistry Ali, Q. Yousuf, S. Shah, M.R. Ng, S.W. tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate |
| title | tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate |
| title_full | tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate |
| title_fullStr | tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate |
| title_full_unstemmed | tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate |
| title_short | tert-Butyl 2-[4-(2-{4-[(tert-butoxycarbonyl)methoxy]-3-methylphenyl}-2-propyl )-2-methylphenoxy]acetate |
| title_sort | tert butyl 2 4 2 4 tert butoxycarbonyl methoxy 3 methylphenyl 2 propyl 2 methylphenoxy acetate |
| topic | QD Chemistry |
| work_keys_str_mv | AT aliq tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate AT yousufs tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate AT shahmr tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate AT ngsw tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate |