[mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate
The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]center dot CH(2)Cl(2),which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1: 1 dichloromethane solvate, which is disordered about a centre of inversion. There is a small deviation from line...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720312994463744 |
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| author | Ho, S.Y. Tiekink, E.R.T. |
| author_facet | Ho, S.Y. Tiekink, E.R.T. |
| author_sort | Ho, S.Y. |
| collection | UM |
| description | The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]center dot CH(2)Cl(2),which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1: 1 dichloromethane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1-Au-P1 angle is 175.35 (5)degrees] which is due to an intramolecular Au center dot center dot center dot O contact [3.080 (5) angstrom]. The primary intermolecular contacts between binuclear molecules are of the type C-H center dot center dot center dot pi, and are arranged so as to form columns in the a-axis direction in which the disordered solvent molecules reside. |
| first_indexed | 2024-03-06T05:33:13Z |
| format | Article |
| id | um.eprints-13218 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:33:13Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-132182019-01-31T04:23:05Z http://eprints.um.edu.my/13218/ [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate Ho, S.Y. Tiekink, E.R.T. Q Science (General) The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]center dot CH(2)Cl(2),which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1: 1 dichloromethane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1-Au-P1 angle is 175.35 (5)degrees] which is due to an intramolecular Au center dot center dot center dot O contact [3.080 (5) angstrom]. The primary intermolecular contacts between binuclear molecules are of the type C-H center dot center dot center dot pi, and are arranged so as to form columns in the a-axis direction in which the disordered solvent molecules reside. International Union of Crystallography 2010 Article PeerReviewed Ho, S.Y. and Tiekink, E.R.T. (2010) [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (6). M608-U181. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Ho, S.Y. Tiekink, E.R.T. [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate |
| title | [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate |
| title_full | [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate |
| title_fullStr | [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate |
| title_full_unstemmed | [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate |
| title_short | [mu-1,1 `-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-kappa S]gold(I)} dichloromethane solvate |
| title_sort | mu 1 1 bis diphenylphosphino ferrocene bis z o ethyl n phenylthiocarbamato kappa s gold i dichloromethane solvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT hosy mu11bisdiphenylphosphinoferrocenebiszoethylnphenylthiocarbamatokappasgoldidichloromethanesolvate AT tiekinkert mu11bisdiphenylphosphinoferrocenebiszoethylnphenylthiocarbamatokappasgoldidichloromethanesolvate |