[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)

The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angs...

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Bibliographic Details
Main Authors: Tadbuppa, P.P., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Description
Summary:The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis by C-H center dot center dot center dot pi interactions.