[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angs...
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International Union of Crystallography
2010
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author | Tadbuppa, P.P. Tiekink, E.R.T. |
author_facet | Tadbuppa, P.P. Tiekink, E.R.T. |
author_sort | Tadbuppa, P.P. |
collection | UM |
description | The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis by C-H center dot center dot center dot pi interactions. |
first_indexed | 2024-03-06T05:33:13Z |
format | Article |
id | um.eprints-13220 |
institution | Universiti Malaya |
last_indexed | 2024-03-06T05:33:13Z |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-132202019-04-16T11:42:16Z http://eprints.um.edu.my/13220/ [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) Tadbuppa, P.P. Tiekink, E.R.T. Q Science (General) The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis by C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (6). M664-U650. ISSN 1600-5368, |
spellingShingle | Q Science (General) Tadbuppa, P.P. Tiekink, E.R.T. [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) |
title | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) |
title_full | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) |
title_fullStr | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) |
title_full_unstemmed | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) |
title_short | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) |
title_sort | z o methyl n 3 chlorophenyl thiocarbamato kappa s triphenylphosphine kappa p gold i |
topic | Q Science (General) |
work_keys_str_mv | AT tadbuppapp zomethyln3chlorophenylthiocarbamatokappastriphenylphosphinekappapgoldi AT tiekinkert zomethyln3chlorophenylthiocarbamatokappastriphenylphosphinekappapgoldi |