[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstro...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720313564889088 |
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| author | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_facet | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_sort | Tadbuppa, P.P. |
| collection | UM |
| description | The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstrom] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C-H center dot center dot center dot N, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions. The solvent molecule is disordered about a twofold rotation axis. |
| first_indexed | 2024-03-06T05:33:14Z |
| format | Article |
| id | um.eprints-13221 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:33:14Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-132212019-01-30T09:01:31Z http://eprints.um.edu.my/13221/ [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate Tadbuppa, P.P. Tiekink, E.R.T. Q Science (General) The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstrom] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C-H center dot center dot center dot N, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions. The solvent molecule is disordered about a twofold rotation axis. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (6). M687-U880. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Tadbuppa, P.P. Tiekink, E.R.T. [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate |
| title | [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate |
| title_full | [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate |
| title_fullStr | [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate |
| title_full_unstemmed | [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate |
| title_short | [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate |
| title_sort | z o ethyl n 4 chlorophenyl thiocarbamato kappa s triphenylphosphine kappa p gold i dichloromethane hemisolvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT tadbuppapp zoethyln4chlorophenylthiocarbamatokappastriphenylphosphinekappapgoldidichloromethanehemisolvate AT tiekinkert zoethyln4chlorophenylthiocarbamatokappastriphenylphosphinekappapgoldidichloromethanehemisolvate |