(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide
The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720322664431616 |
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| author | Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. |
| author_facet | Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. |
| author_sort | Garden, S.J. |
| collection | UM |
| description | The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot center dot N hydrogen bond occurs. Linear supramolecular chains along the b axis mediated by O-H center dot center dot center dot O hydrogen-bonding interactions feature in the crystal structure. These chains are also stabilized by weak C-H center dot center dot center dot N contacts. |
| first_indexed | 2024-03-06T05:33:22Z |
| format | Article |
| id | um.eprints-13272 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:33:22Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-132722019-01-31T04:09:55Z http://eprints.um.edu.my/13272/ (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. QD Chemistry The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot center dot N hydrogen bond occurs. Linear supramolecular chains along the b axis mediated by O-H center dot center dot center dot O hydrogen-bonding interactions feature in the crystal structure. These chains are also stabilized by weak C-H center dot center dot center dot N contacts. International Union of Crystallography 2010 Article PeerReviewed Garden, S.J. and Pinto, A.C. and da Cunha, F.R. and Fontes, S.P. and Lima, A.S. and Tiekink, E.R.T. (2010) (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide. Acta Crystallographica Section E: Structure Reports Online, 66 (6). O1436-U1657. ISSN 1600-5368, |
| spellingShingle | QD Chemistry Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title | (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_full | (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_fullStr | (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_full_unstemmed | (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_short | (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_sort | 2e n 3 5 dibromo 4 methoxyphenyl 2 hydroxyimino acetamide |
| topic | QD Chemistry |
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