5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione
The structure analysis of the title compound, C14H16O2S2, shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead -CH2- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead -CH2- group. The dione-substitu...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: |
| _version_ | 1825720326786383872 |
|---|---|
| author | von Richthofen, A.A. Cardoso Filho, J.E.P. Marzorati, L. Zukerman-Schpector, J. Tiekink, E.R.T. Di Vitta, C. |
| author_facet | von Richthofen, A.A. Cardoso Filho, J.E.P. Marzorati, L. Zukerman-Schpector, J. Tiekink, E.R.T. Di Vitta, C. |
| author_sort | von Richthofen, A.A. |
| collection | UM |
| description | The structure analysis of the title compound, C14H16O2S2, shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead -CH2- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead -CH2- group. The dione-substituted ring adopts a folded conformation about the 1,4-C center dot center dot center dot C vector, with the ketone groups lying to one side. The cyclohexene ring adopts a boat conformation. |
| first_indexed | 2024-03-06T05:33:26Z |
| format | Article |
| id | um.eprints-13294 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:33:26Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-132942019-01-30T08:33:20Z http://eprints.um.edu.my/13294/ 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione von Richthofen, A.A. Cardoso Filho, J.E.P. Marzorati, L. Zukerman-Schpector, J. Tiekink, E.R.T. Di Vitta, C. QD Chemistry The structure analysis of the title compound, C14H16O2S2, shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead -CH2- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead -CH2- group. The dione-substituted ring adopts a folded conformation about the 1,4-C center dot center dot center dot C vector, with the ketone groups lying to one side. The cyclohexene ring adopts a boat conformation. International Union of Crystallography 2010 Article PeerReviewed von Richthofen, A.A. and Cardoso Filho, J.E.P. and Marzorati, L. and Zukerman-Schpector, J. and Tiekink, E.R.T. and Di Vitta, C. (2010) 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione. Acta Crystallographica Section E: Structure Reports Online, 66 (6). O1259-U131. ISSN 1600-5368, |
| spellingShingle | QD Chemistry von Richthofen, A.A. Cardoso Filho, J.E.P. Marzorati, L. Zukerman-Schpector, J. Tiekink, E.R.T. Di Vitta, C. 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione |
| title | 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione |
| title_full | 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione |
| title_fullStr | 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione |
| title_full_unstemmed | 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione |
| title_short | 5-Methyl-2,4-bis(methylsulfanyl)tricyclo[6.2.1.0(2,7)]undeca-4,9-diene -3,6-dione |
| title_sort | 5 methyl 2 4 bis methylsulfanyl tricyclo 6 2 1 0 2 7 undeca 4 9 diene 3 6 dione |
| topic | QD Chemistry |
| work_keys_str_mv | AT vonrichthofenaa 5methyl24bismethylsulfanyltricyclo621027undeca49diene36dione AT cardosofilhojep 5methyl24bismethylsulfanyltricyclo621027undeca49diene36dione AT marzoratil 5methyl24bismethylsulfanyltricyclo621027undeca49diene36dione AT zukermanschpectorj 5methyl24bismethylsulfanyltricyclo621027undeca49diene36dione AT tiekinkert 5methyl24bismethylsulfanyltricyclo621027undeca49diene36dione AT divittac 5methyl24bismethylsulfanyltricyclo621027undeca49diene36dione |