Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics
The influence of sonoluminescence transesterification on biodiesel physicochemical properties was investigated and the results were compared to those of traditional mechanical stirring. This study was conducted to identify the mechanistic features of ultra sonication by coupling statistical analysis...
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| Format: | Article |
| Language: | English |
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2015
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| Online Access: | http://eprints.um.edu.my/13860/1/Mechanistic_analysis_of_cavitation_assisted.pdf |
| _version_ | 1825720428371378176 |
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| author | Sajjadi, B. Abdul Raman, Abdul Aziz Ibrahim, Shaliza |
| author_facet | Sajjadi, B. Abdul Raman, Abdul Aziz Ibrahim, Shaliza |
| author_sort | Sajjadi, B. |
| collection | UM |
| description | The influence of sonoluminescence transesterification on biodiesel physicochemical properties was investigated and the results were compared to those of traditional mechanical stirring. This study was conducted to identify the mechanistic features of ultra sonication by coupling statistical analysis of the experiments into the simulation of cavitation bubble. Different combinations of operational variables were employed for alkali-catalysis transesterification of palm oil. The experimental results showed that transesterification with ultrasound irradiation could change the biodiesel density by about 0.3 kg/m(3); the viscosity by 0.12 mm(2)/s; the pour point by about 1-2 degrees C and the flash point by 5 degrees C compared to the traditional method. Furthermore, 93.84 of yield with alcohol to oil molar ratio of 6:1 could be achieved through ultrasound assisted transesterification within only 20 min. However, only 89.09 of reaction yield was obtained by traditional macro mixing/heating under the same condition. Based on the simulated oscillation velocity value, the cavitation phenomenon significantly contributed to generation of fine micro emulsion and was able to overcome mass transfer restriction. It was found that the sonoluminescence bubbles reached the temperature of 758-713 K, pressure of 235.5-159.55 bar, oscillation velocity of 3.5-6.5 cm/s, and equilibrium radius of 17.9-13.7 times greater than its initial size under the ambient temperature of 50-64 degrees C at the moment of collapse. This showed that the sonoluminescence bubbles were in the condition in which the decomposition phenomena were activated and the reaction rate was accelerated together with a change in the biodiesel properties. (C) 2014 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-06T05:35:00Z |
| format | Article |
| id | um.eprints-13860 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:35:00Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | um.eprints-138602019-12-06T07:58:53Z http://eprints.um.edu.my/13860/ Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics Sajjadi, B. Abdul Raman, Abdul Aziz Ibrahim, Shaliza T Technology (General) TP Chemical technology The influence of sonoluminescence transesterification on biodiesel physicochemical properties was investigated and the results were compared to those of traditional mechanical stirring. This study was conducted to identify the mechanistic features of ultra sonication by coupling statistical analysis of the experiments into the simulation of cavitation bubble. Different combinations of operational variables were employed for alkali-catalysis transesterification of palm oil. The experimental results showed that transesterification with ultrasound irradiation could change the biodiesel density by about 0.3 kg/m(3); the viscosity by 0.12 mm(2)/s; the pour point by about 1-2 degrees C and the flash point by 5 degrees C compared to the traditional method. Furthermore, 93.84 of yield with alcohol to oil molar ratio of 6:1 could be achieved through ultrasound assisted transesterification within only 20 min. However, only 89.09 of reaction yield was obtained by traditional macro mixing/heating under the same condition. Based on the simulated oscillation velocity value, the cavitation phenomenon significantly contributed to generation of fine micro emulsion and was able to overcome mass transfer restriction. It was found that the sonoluminescence bubbles reached the temperature of 758-713 K, pressure of 235.5-159.55 bar, oscillation velocity of 3.5-6.5 cm/s, and equilibrium radius of 17.9-13.7 times greater than its initial size under the ambient temperature of 50-64 degrees C at the moment of collapse. This showed that the sonoluminescence bubbles were in the condition in which the decomposition phenomena were activated and the reaction rate was accelerated together with a change in the biodiesel properties. (C) 2014 Elsevier B.V. All rights reserved. 2015-01 Article PeerReviewed application/pdf en http://eprints.um.edu.my/13860/1/Mechanistic_analysis_of_cavitation_assisted.pdf Sajjadi, B. and Abdul Raman, Abdul Aziz and Ibrahim, Shaliza (2015) Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics. Ultrasonics Sonochemistry, 22. pp. 463-473. ISSN 1350-4177, DOI https://doi.org/10.1016/j.ultsonch.2014.06.004 <https://doi.org/10.1016/j.ultsonch.2014.06.004>. http://www.sciencedirect.com/science/article/pii/S1350417714001904 10.1016/j.ultsonch.2014.06.004 |
| spellingShingle | T Technology (General) TP Chemical technology Sajjadi, B. Abdul Raman, Abdul Aziz Ibrahim, Shaliza Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| title | Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| title_full | Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| title_fullStr | Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| title_full_unstemmed | Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| title_short | Mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| title_sort | mechanistic analysis of cavitation assisted transesterification on biodiesel characteristics |
| topic | T Technology (General) TP Chemical technology |
| url | http://eprints.um.edu.my/13860/1/Mechanistic_analysis_of_cavitation_assisted.pdf |
| work_keys_str_mv | AT sajjadib mechanisticanalysisofcavitationassistedtransesterificationonbiodieselcharacteristics AT abdulramanabdulaziz mechanisticanalysisofcavitationassistedtransesterificationonbiodieselcharacteristics AT ibrahimshaliza mechanisticanalysisofcavitationassistedtransesterificationonbiodieselcharacteristics |