Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids...
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| Format: | Article |
| Language: | English |
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Springer Verlag (Germany)
2015
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| Online Access: | http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf |
| _version_ | 1825720456455389184 |
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| author | Hayyan, M. Hashim, M.A. AlNashef, I.M. |
| author_facet | Hayyan, M. Hashim, M.A. AlNashef, I.M. |
| author_sort | Hayyan, M. |
| collection | UM |
| description | The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids (ILs) and determine the rate constants based on pseudo 1st- and 2nd-order reactions between the IL and O-2 (aEuro cent a') generated in DMSO. O-2 (aEuro cent a') was unstable in DMSO containing S-222TFSI, DMImMS, BDMImTfO, EMImTFSI, EMImMS, P-14,P-666TPTP, P-14,P-666TFSI, and all pyridinium-based ILs. In contrast, O-2 (aEuro cent a') was very stable in DMSO containing MOPMPipTFSI, BMPyrrDCA, BMPyrrTFSI, BMPyrrTfO, HMPyrrTFSI, MOEMPipTPTP, BMPyrrTFA, N-112,1O(2)TFSI, and MOEMMorTFSI. This shows that these ILs can be used for different applications involving O-2 (aEuro cent a'). The reaction rate constant, total consumption, and consumption rate of O-2 (aEuro cent a') were determined. The rate constants of O-2 (aEuro cent a') in some ILs were found to follow pseudo 1st-order reaction, while in others, pseudo 2nd-order reaction kinetics were observed. |
| first_indexed | 2024-03-06T05:35:25Z |
| format | Article |
| id | um.eprints-14014 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:35:25Z |
| publishDate | 2015 |
| publisher | Springer Verlag (Germany) |
| record_format | dspace |
| spelling | um.eprints-140142015-09-01T08:06:59Z http://eprints.um.edu.my/14014/ Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids Hayyan, M. Hashim, M.A. AlNashef, I.M. T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids (ILs) and determine the rate constants based on pseudo 1st- and 2nd-order reactions between the IL and O-2 (aEuro cent a') generated in DMSO. O-2 (aEuro cent a') was unstable in DMSO containing S-222TFSI, DMImMS, BDMImTfO, EMImTFSI, EMImMS, P-14,P-666TPTP, P-14,P-666TFSI, and all pyridinium-based ILs. In contrast, O-2 (aEuro cent a') was very stable in DMSO containing MOPMPipTFSI, BMPyrrDCA, BMPyrrTFSI, BMPyrrTfO, HMPyrrTFSI, MOEMPipTPTP, BMPyrrTFA, N-112,1O(2)TFSI, and MOEMMorTFSI. This shows that these ILs can be used for different applications involving O-2 (aEuro cent a'). The reaction rate constant, total consumption, and consumption rate of O-2 (aEuro cent a') were determined. The rate constants of O-2 (aEuro cent a') in some ILs were found to follow pseudo 1st-order reaction, while in others, pseudo 2nd-order reaction kinetics were observed. Springer Verlag (Germany) 2015-03 Article PeerReviewed application/pdf en http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf Hayyan, M. and Hashim, M.A. and AlNashef, I.M. (2015) Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids. Ionics, 21 (3). pp. 719-728. ISSN 0947-7047, DOI https://doi.org/10.1007/s11581-014-1224-y <https://doi.org/10.1007/s11581-014-1224-y>. http://link.springer.com/article/10.1007%2Fs11581-014-1224-y DOI: 10.1007/s11581-014-1224-y |
| spellingShingle | T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Hayyan, M. Hashim, M.A. AlNashef, I.M. Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title | Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_full | Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_fullStr | Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_full_unstemmed | Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_short | Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_sort | kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| topic | T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf |
| work_keys_str_mv | AT hayyanm kineticsofsuperoxideionindimethylsulfoxidecontainingionicliquids AT hashimma kineticsofsuperoxideionindimethylsulfoxidecontainingionicliquids AT alnashefim kineticsofsuperoxideionindimethylsulfoxidecontainingionicliquids |