The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase

Synthesis of bio-lubricant from palm oil mill effluent (POME) using enzymatic hydrolysis and noncatalytic esterification has been investigated in this article. The effects of essential parameters, which are temperature, pH, agitation speed, enzyme loading, ratio of oil to fatty acid and alcohol to f...

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Main Authors: Syaima, M.T.S., Ong, K.H., Noor, Ishenny Mohd, Zamratul, M.I.M., Brahim, S.A., Hafizul, M.M.
Format: Article
Language:English
Published: Elsevier 2015
Subjects:
Online Access:http://eprints.um.edu.my/14038/1/The_synthesis_of_bio-lubricant_based_oil_by_hydrolysis_and_non.pdf
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author Syaima, M.T.S.
Ong, K.H.
Noor, Ishenny Mohd
Zamratul, M.I.M.
Brahim, S.A.
Hafizul, M.M.
author_facet Syaima, M.T.S.
Ong, K.H.
Noor, Ishenny Mohd
Zamratul, M.I.M.
Brahim, S.A.
Hafizul, M.M.
author_sort Syaima, M.T.S.
collection UM
description Synthesis of bio-lubricant from palm oil mill effluent (POME) using enzymatic hydrolysis and noncatalytic esterification has been investigated in this article. The effects of essential parameters, which are temperature, pH, agitation speed, enzyme loading, ratio of oil to fatty acid and alcohol to fatty acid, on the reaction rate were examined. The optimum hydrolysis rate (0.1639 mg/sec.L) was achieved at 40 degrees C, pH 7.0, 650 rpm, 20 U/mL of enzyme loading and 50 (v/v) of POME. As for non-catalytic esterification, the highest reaction rate attained was 0.0018 mg/sec.L at the operating conditions of 75 degrees C, 950 rpm, and alcohol to fatty acid ratio of 3:1. Viscosity and density of the produced bio-lubricant were also evaluated. (C) 2015 Elsevier Ltd. All rights reserved.
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spelling um.eprints-140382019-11-08T08:26:05Z http://eprints.um.edu.my/14038/ The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase Syaima, M.T.S. Ong, K.H. Noor, Ishenny Mohd Zamratul, M.I.M. Brahim, S.A. Hafizul, M.M. T Technology (General) TP Chemical technology Synthesis of bio-lubricant from palm oil mill effluent (POME) using enzymatic hydrolysis and noncatalytic esterification has been investigated in this article. The effects of essential parameters, which are temperature, pH, agitation speed, enzyme loading, ratio of oil to fatty acid and alcohol to fatty acid, on the reaction rate were examined. The optimum hydrolysis rate (0.1639 mg/sec.L) was achieved at 40 degrees C, pH 7.0, 650 rpm, 20 U/mL of enzyme loading and 50 (v/v) of POME. As for non-catalytic esterification, the highest reaction rate attained was 0.0018 mg/sec.L at the operating conditions of 75 degrees C, 950 rpm, and alcohol to fatty acid ratio of 3:1. Viscosity and density of the produced bio-lubricant were also evaluated. (C) 2015 Elsevier Ltd. All rights reserved. Elsevier 2015-04 Article PeerReviewed application/pdf en http://eprints.um.edu.my/14038/1/The_synthesis_of_bio-lubricant_based_oil_by_hydrolysis_and_non.pdf Syaima, M.T.S. and Ong, K.H. and Noor, Ishenny Mohd and Zamratul, M.I.M. and Brahim, S.A. and Hafizul, M.M. (2015) The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase. Renewable and Sustainable Energy Reviews, 44. pp. 669-675. ISSN 1364-0321, DOI https://doi.org/10.1016/j.rser.2015.01.005 <https://doi.org/10.1016/j.rser.2015.01.005>. https://doi.org/10.1016/j.rser.2015.01.005 doi:10.1016/j.rser.2015.01.005
spellingShingle T Technology (General)
TP Chemical technology
Syaima, M.T.S.
Ong, K.H.
Noor, Ishenny Mohd
Zamratul, M.I.M.
Brahim, S.A.
Hafizul, M.M.
The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase
title The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase
title_full The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase
title_fullStr The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase
title_full_unstemmed The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase
title_short The synthesis of bio-lubricant based oil by hydrolysis and non-catalytic of palm oil mill effluent (POME) using lipase
title_sort synthesis of bio lubricant based oil by hydrolysis and non catalytic of palm oil mill effluent pome using lipase
topic T Technology (General)
TP Chemical technology
url http://eprints.um.edu.my/14038/1/The_synthesis_of_bio-lubricant_based_oil_by_hydrolysis_and_non.pdf
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