n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate
The monodeprotonated Schiff base ligand in the title compound, [Sn(C4H9)(C19H21N4S)Cl-2]center dot CHCl3, N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below whic...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720492139479040 |
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| author | Abu Affan, M. Salam, M.A. Farina, Y. Ng, S.W. |
| author_facet | Abu Affan, M. Salam, M.A. Farina, Y. Ng, S.W. |
| author_sort | Abu Affan, M. |
| collection | UM |
| description | The monodeprotonated Schiff base ligand in the title compound, [Sn(C4H9)(C19H21N4S)Cl-2]center dot CHCl3, N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloroform molecule are disordered over two positions in an 0.67: 0.33 ratio. |
| first_indexed | 2024-03-06T05:35:58Z |
| format | Article |
| id | um.eprints-14272 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:35:58Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-142722019-01-31T01:38:30Z http://eprints.um.edu.my/14272/ n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate Abu Affan, M. Salam, M.A. Farina, Y. Ng, S.W. Q Science (General) The monodeprotonated Schiff base ligand in the title compound, [Sn(C4H9)(C19H21N4S)Cl-2]center dot CHCl3, N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloroform molecule are disordered over two positions in an 0.67: 0.33 ratio. International Union of Crystallography 2010 Article PeerReviewed Abu Affan, M. and Salam, M.A. and Farina, Y. and Ng, S.W. (2010) n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (5). M571-U950. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Abu Affan, M. Salam, M.A. Farina, Y. Ng, S.W. n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate |
| title | n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate |
| title_full | n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate |
| title_fullStr | n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate |
| title_full_unstemmed | n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate |
| title_short | n-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-kappa N)methylene]thiosemicarbazidato-kappa N-2(1),S}tin(IV) chloroform monosolvate |
| title_sort | n butyldichlorido 4 cyclohexyl 1 phenyl 2 pyridyl kappa n methylene thiosemicarbazidato kappa n 2 1 s tin iv chloroform monosolvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT abuaffanm nbutyldichlorido4cyclohexyl1phenyl2pyridylkappanmethylenethiosemicarbazidatokappan21stinivchloroformmonosolvate AT salamma nbutyldichlorido4cyclohexyl1phenyl2pyridylkappanmethylenethiosemicarbazidatokappan21stinivchloroformmonosolvate AT farinay nbutyldichlorido4cyclohexyl1phenyl2pyridylkappanmethylenethiosemicarbazidatokappan21stinivchloroformmonosolvate AT ngsw nbutyldichlorido4cyclohexyl1phenyl2pyridylkappanmethylenethiosemicarbazidatokappan21stinivchloroformmonosolvate |