[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S, P-donor set [S-Au-P = 177.62 (5)degrees]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720493105217536 |
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| author | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_facet | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_sort | Tadbuppa, P.P. |
| collection | UM |
| description | The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S, P-donor set [S-Au-P = 177.62 (5)degrees]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) angstrom. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group. |
| first_indexed | 2024-03-06T05:35:59Z |
| format | Article |
| id | um.eprints-14277 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:35:59Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-142772019-01-30T09:00:08Z http://eprints.um.edu.my/14277/ [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) Tadbuppa, P.P. Tiekink, E.R.T. Q Science (General) The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S, P-donor set [S-Au-P = 177.62 (5)degrees]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) angstrom. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (5). M498-U309. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Tadbuppa, P.P. Tiekink, E.R.T. [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title | [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_full | [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_fullStr | [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_full_unstemmed | [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_short | [O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_sort | o ethyl z n 2 chlorophenyl thiocarbamato kappa s tricyclohexylphosphine kappa p gold i |
| topic | Q Science (General) |
| work_keys_str_mv | AT tadbuppapp oethylzn2chlorophenylthiocarbamatokappastricyclohexylphosphinekappapgoldi AT tiekinkert oethylzn2chlorophenylthiocarbamatokappastricyclohexylphosphinekappapgoldi |