mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride
The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyri...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946744140890112 |
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| author | Tiekink, E.R.T. Wardell, J.L. Fernandes, C. Horn, A. Skakle, J.M.S. |
| author_facet | Tiekink, E.R.T. Wardell, J.L. Fernandes, C. Horn, A. Skakle, J.M.S. |
| author_sort | Tiekink, E.R.T. |
| collection | UM |
| description | The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N(3)O(3) donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds. |
| first_indexed | 2024-03-06T05:36:27Z |
| format | Article |
| id | um.eprints-14446 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:36:27Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-144462019-01-30T08:43:11Z http://eprints.um.edu.my/14446/ mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride Tiekink, E.R.T. Wardell, J.L. Fernandes, C. Horn, A. Skakle, J.M.S. QC Physics The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N(3)O(3) donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed Tiekink, E.R.T. and Wardell, J.L. and Fernandes, C. and Horn, A. and Skakle, J.M.S. (2010) mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66 (5). M566-U904. ISSN 1600-5368, |
| spellingShingle | QC Physics Tiekink, E.R.T. Wardell, J.L. Fernandes, C. Horn, A. Skakle, J.M.S. mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride |
| title | mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride |
| title_full | mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride |
| title_fullStr | mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride |
| title_full_unstemmed | mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride |
| title_short | mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride |
| title_sort | mu acetato bis mu 2 3 chloro 2 hydroxypropyl 2 pyridylmethyl amin o methyl phenolato dinickel ii chloride |
| topic | QC Physics |
| work_keys_str_mv | AT tiekinkert muacetatobismu23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride AT wardelljl muacetatobismu23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride AT fernandesc muacetatobismu23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride AT horna muacetatobismu23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride AT skaklejms muacetatobismu23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride |