1,1 `-Methylenedipyridinium dichloride monohydrate
In the crystal structure of the title salt, C(11)H(12)N(2)(2+)center dot 2Cl(-)center dot H(2)O, the dication adopts a butterfly shape [dihedral angle between rings = 69.0 (1)degrees] with the water molecule lying in the V-shaped cavity. Each O-H bond of the water molecule lies parallel to an aromat...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946745310052352 |
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| author | Fu, Wen-Zhen Wang, Wei-Juan Niu, Yun-Yin Ng, S.W. |
| author_facet | Fu, Wen-Zhen Wang, Wei-Juan Niu, Yun-Yin Ng, S.W. |
| author_sort | Fu, Wen-Zhen |
| collection | UM |
| description | In the crystal structure of the title salt, C(11)H(12)N(2)(2+)center dot 2Cl(-)center dot H(2)O, the dication adopts a butterfly shape [dihedral angle between rings = 69.0 (1)degrees] with the water molecule lying in the V-shaped cavity. Each O-H bond of the water molecule lies parallel to an aromatic ring and forms an O-H center dot center dot center dot Cl interaction to a chloride anion. The methylene C atom in the dication and the water O atoms lie on special positions of twofold site symmetry. |
| first_indexed | 2024-03-06T05:36:28Z |
| format | Article |
| id | um.eprints-14452 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:36:28Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-144522019-01-31T04:05:23Z http://eprints.um.edu.my/14452/ 1,1 `-Methylenedipyridinium dichloride monohydrate Fu, Wen-Zhen Wang, Wei-Juan Niu, Yun-Yin Ng, S.W. QC Physics In the crystal structure of the title salt, C(11)H(12)N(2)(2+)center dot 2Cl(-)center dot H(2)O, the dication adopts a butterfly shape [dihedral angle between rings = 69.0 (1)degrees] with the water molecule lying in the V-shaped cavity. Each O-H bond of the water molecule lies parallel to an aromatic ring and forms an O-H center dot center dot center dot Cl interaction to a chloride anion. The methylene C atom in the dication and the water O atoms lie on special positions of twofold site symmetry. International Union of Crystallography 2010 Article PeerReviewed Fu, Wen-Zhen and Wang, Wei-Juan and Niu, Yun-Yin and Ng, S.W. (2010) 1,1 `-Methylenedipyridinium dichloride monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (5). O1211-U1214. ISSN 1600-5368, |
| spellingShingle | QC Physics Fu, Wen-Zhen Wang, Wei-Juan Niu, Yun-Yin Ng, S.W. 1,1 `-Methylenedipyridinium dichloride monohydrate |
| title | 1,1 `-Methylenedipyridinium dichloride monohydrate |
| title_full | 1,1 `-Methylenedipyridinium dichloride monohydrate |
| title_fullStr | 1,1 `-Methylenedipyridinium dichloride monohydrate |
| title_full_unstemmed | 1,1 `-Methylenedipyridinium dichloride monohydrate |
| title_short | 1,1 `-Methylenedipyridinium dichloride monohydrate |
| title_sort | 1 1 methylenedipyridinium dichloride monohydrate |
| topic | QC Physics |
| work_keys_str_mv | AT fuwenzhen 11methylenedipyridiniumdichloridemonohydrate AT wangweijuan 11methylenedipyridiniumdichloridemonohydrate AT niuyunyin 11methylenedipyridiniumdichloridemonohydrate AT ngsw 11methylenedipyridiniumdichloridemonohydrate |