N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate
In the asymmetric unit of the title compound, C19H27ClN4O·0.5C2H6O·1.5H2O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH–N=CH– chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three molecul...
| Autores principales: | , , , , |
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| Formato: | Artículo |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | http://eprints.um.edu.my/145/1/e-66-o2131.pdf |
| _version_ | 1825718417570660352 |
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| author | Abdul-Malek, S.Al-Tamimi Ahmed, B. Mohamed, A. Al-Omar Ali A, El-Emam Ng, Seik Weng |
| author_facet | Abdul-Malek, S.Al-Tamimi Ahmed, B. Mohamed, A. Al-Omar Ali A, El-Emam Ng, Seik Weng |
| author_sort | Abdul-Malek, S.Al-Tamimi |
| collection | UM |
| description | In the asymmetric unit of the title compound, C19H27ClN4O·0.5C2H6O·1.5H2O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH–N=CH– chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three molecules of water and one molecule of ethanol. In both independent molecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water molecules; these are linked to other acceptor atoms, generating a layer structure. O—H[cdots, three dots, centered]O and O—H[cdots, three dots, centered]N interactions involving the water molecules also occur. |
| first_indexed | 2024-03-06T05:04:18Z |
| format | Article |
| id | um.eprints-145 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:04:18Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-1452020-02-12T02:37:36Z http://eprints.um.edu.my/145/ N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate Abdul-Malek, S.Al-Tamimi Ahmed, B. Mohamed, A. Al-Omar Ali A, El-Emam Ng, Seik Weng QD Chemistry In the asymmetric unit of the title compound, C19H27ClN4O·0.5C2H6O·1.5H2O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH–N=CH– chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three molecules of water and one molecule of ethanol. In both independent molecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water molecules; these are linked to other acceptor atoms, generating a layer structure. O—H[cdots, three dots, centered]O and O—H[cdots, three dots, centered]N interactions involving the water molecules also occur. International Union of Crystallography 2010-03 Article NonPeerReviewed application/pdf en http://eprints.um.edu.my/145/1/e-66-o2131.pdf Abdul-Malek, S.Al-Tamimi and Ahmed, B. and Mohamed, A. Al-Omar and Ali A, El-Emam and Ng, Seik Weng (2010) N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). o2131. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536810029260 <https://doi.org/10.1107/S1600536810029260>. https://doi.org/10.1107/S1600536810029260 doi:10.1107/S1600536810029260 |
| spellingShingle | QD Chemistry Abdul-Malek, S.Al-Tamimi Ahmed, B. Mohamed, A. Al-Omar Ali A, El-Emam Ng, Seik Weng N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate |
| title | N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate |
| title_full | N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate |
| title_fullStr | N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate |
| title_full_unstemmed | N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate |
| title_short | N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbohydrazide sesquihydrate ethanol hemisolvate |
| title_sort | n 2 n butyl 4 chloro 1h imidazol 5 yl methyl idene adamantane 1 carbo hydrazide sesquihydrate ethanol hemi solvate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/145/1/e-66-o2131.pdf |
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