Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium]
In the crystal structure of the polymeric title compound, [Sr(C10H6O6S2)(H2O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO3 unit to bind to two Sr-II cations and the other -SO3 unit to bind to three Sr-II cations; of the two coordinated water molecules, one is monodentate to one SrII...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1796946778108461056 |
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| author | Gao, S. Ng, S.W. |
| author_facet | Gao, S. Ng, S.W. |
| author_sort | Gao, S. |
| collection | UM |
| description | In the crystal structure of the polymeric title compound, [Sr(C10H6O6S2)(H2O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO3 unit to bind to two Sr-II cations and the other -SO3 unit to bind to three Sr-II cations; of the two coordinated water molecules, one is monodentate to one SrII cation, whereas the other bridges two Sr-II cations. The mu(5)-bridging mode of the dianon and the mu(2)-bridging mode of the water molecule generate a polymeric three-dimensional network which is consolidated by O-H center dot center dot center dot O hydrogen bonds. The Sr-II cation exists in an undefined eight-coordinate environment. |
| first_indexed | 2024-03-06T05:36:57Z |
| format | Article |
| id | um.eprints-14648 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:36:57Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-146482019-01-31T04:07:54Z http://eprints.um.edu.my/14648/ Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] Gao, S. Ng, S.W. QC Physics In the crystal structure of the polymeric title compound, [Sr(C10H6O6S2)(H2O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO3 unit to bind to two Sr-II cations and the other -SO3 unit to bind to three Sr-II cations; of the two coordinated water molecules, one is monodentate to one SrII cation, whereas the other bridges two Sr-II cations. The mu(5)-bridging mode of the dianon and the mu(2)-bridging mode of the water molecule generate a polymeric three-dimensional network which is consolidated by O-H center dot center dot center dot O hydrogen bonds. The Sr-II cation exists in an undefined eight-coordinate environment. International Union of Crystallography 2011 Article PeerReviewed Gao, S. and Ng, S.W. (2011) Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium]. Acta Crystallographica Section E: Structure Reports Online, 67 (12). M1787-U1482. ISSN 1600-5368, |
| spellingShingle | QC Physics Gao, S. Ng, S.W. Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] |
| title | Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] |
| title_full | Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] |
| title_fullStr | Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] |
| title_full_unstemmed | Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] |
| title_short | Poly[mu(2)-aqua-aqua-mu(5)-naphthalene-2,7-disulfonato-strontium] |
| title_sort | poly mu 2 aqua aqua mu 5 naphthalene 2 7 disulfonato strontium |
| topic | QC Physics |
| work_keys_str_mv | AT gaos polymu2aquaaquamu5naphthalene27disulfonatostrontium AT ngsw polymu2aquaaquamu5naphthalene27disulfonatostrontium |