Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate
In the crystal structure of the title salt, [Ag(NH(3))(2)](4)-(C(7)H(6)O(7)S(2))(2)center dot H(2)O, the four independent Ag(I) complex cations all lie on special positions of m site symmetry, as do the two independent 2-hydroxy-5-methylbenzene-1,3-disulfonate anions. The Ag(I) cations exist in an a...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1796946779490484224 |
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| author | Zhang, Li-Wei Gao, S. Ng, S.W. |
| author_facet | Zhang, Li-Wei Gao, S. Ng, S.W. |
| author_sort | Zhang, Li-Wei |
| collection | UM |
| description | In the crystal structure of the title salt, [Ag(NH(3))(2)](4)-(C(7)H(6)O(7)S(2))(2)center dot H(2)O, the four independent Ag(I) complex cations all lie on special positions of m site symmetry, as do the two independent 2-hydroxy-5-methylbenzene-1,3-disulfonate anions. The Ag(I) cations exist in an almost linear coordination geometry [N-Ag-N = 175.2 (2), 178.08 (16), 175.8 (2) and 178.20 (19)degrees]. The water molecule is disordered about a mirror plane. Two independent complex cations are linked by an Ag center dot center dot center dot Ag interaction of 3.3151 (1) angstrom, furnishing a linear [Ag(NH(3))(2)](n) polycationic chain running along b. The free complex cations, polycationic chain and 2-hydroxy-5-methylbenzene-1,3-disulfonate anions interact via N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional network. |
| first_indexed | 2024-03-06T05:36:59Z |
| format | Article |
| id | um.eprints-14655 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:36:59Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-146552019-01-30T08:14:00Z http://eprints.um.edu.my/14655/ Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate Zhang, Li-Wei Gao, S. Ng, S.W. QC Physics In the crystal structure of the title salt, [Ag(NH(3))(2)](4)-(C(7)H(6)O(7)S(2))(2)center dot H(2)O, the four independent Ag(I) complex cations all lie on special positions of m site symmetry, as do the two independent 2-hydroxy-5-methylbenzene-1,3-disulfonate anions. The Ag(I) cations exist in an almost linear coordination geometry [N-Ag-N = 175.2 (2), 178.08 (16), 175.8 (2) and 178.20 (19)degrees]. The water molecule is disordered about a mirror plane. Two independent complex cations are linked by an Ag center dot center dot center dot Ag interaction of 3.3151 (1) angstrom, furnishing a linear [Ag(NH(3))(2)](n) polycationic chain running along b. The free complex cations, polycationic chain and 2-hydroxy-5-methylbenzene-1,3-disulfonate anions interact via N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011 Article PeerReviewed Zhang, Li-Wei and Gao, S. and Ng, S.W. (2011) Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (12). M1780-U1533. ISSN 1600-5368, |
| spellingShingle | QC Physics Zhang, Li-Wei Gao, S. Ng, S.W. Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate |
| title | Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate |
| title_full | Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate |
| title_fullStr | Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate |
| title_full_unstemmed | Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate |
| title_short | Tetrakis[diamminesilver(I)] bis(2-hydroxy-5-methylbenzene-1,3-disulfonate) monohydrate |
| title_sort | tetrakis diamminesilver i bis 2 hydroxy 5 methylbenzene 1 3 disulfonate monohydrate |
| topic | QC Physics |
| work_keys_str_mv | AT zhangliwei tetrakisdiamminesilveribis2hydroxy5methylbenzene13disulfonatemonohydrate AT gaos tetrakisdiamminesilveribis2hydroxy5methylbenzene13disulfonatemonohydrate AT ngsw tetrakisdiamminesilveribis2hydroxy5methylbenzene13disulfonatemonohydrate |