Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1796946781045522432 |
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| author | Ou, Guang-Chuan Ng, S.W. |
| author_facet | Ou, Guang-Chuan Ng, S.W. |
| author_sort | Ou, Guang-Chuan |
| collection | UM |
| description | In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted ZnN4O trigonal bipyramid; for the other, the acetate group is anisobidentate and the geometry is a distorted ZnN4O2 octahedron. The two macrocycle-zinc acetate units are bridged through a diperchloratosodium unit. In the crystal, the complex cations and uncoordinated perchlorate anions are linked by N-H center dot center dot center dot O hydrogen bonds. |
| first_indexed | 2024-03-06T05:37:00Z |
| format | Article |
| id | um.eprints-14664 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:00Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-146642019-01-31T05:11:14Z http://eprints.um.edu.my/14664/ Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate Ou, Guang-Chuan Ng, S.W. QC Physics In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted ZnN4O trigonal bipyramid; for the other, the acetate group is anisobidentate and the geometry is a distorted ZnN4O2 octahedron. The two macrocycle-zinc acetate units are bridged through a diperchloratosodium unit. In the crystal, the complex cations and uncoordinated perchlorate anions are linked by N-H center dot center dot center dot O hydrogen bonds. International Union of Crystallography 2011 Article PeerReviewed Ou, Guang-Chuan and Ng, S.W. (2011) Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate. Acta Crystallographica Section E: Structure Reports Online, 67 (12). O1664-U1342. ISSN 1600-5368, |
| spellingShingle | QC Physics Ou, Guang-Chuan Ng, S.W. Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate |
| title | Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate |
| title_full | Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate |
| title_fullStr | Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate |
| title_full_unstemmed | Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate |
| title_short | Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate |
| title_sort | di mu acetato 1 2 kappa o 2 o 2 3 kappa o 3 o o bis 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane 1 kappa n 4 3 kappa n 4 bis perchlorato 2 kappa o 2 o 2 sodium 1 3 dizinc perchlorate |
| topic | QC Physics |
| work_keys_str_mv | AT ouguangchuan dimuacetato12kappao2o23kappao3oobis557121214hexamethyl14811tetraazacyclotetradecane1kappan43kappan4bisperchlorato2kappao2o2sodium13dizincperchlorate AT ngsw dimuacetato12kappao2o23kappao3oobis557121214hexamethyl14811tetraazacyclotetradecane1kappan43kappan4bisperchlorato2kappao2o2sodium13dizincperchlorate |