Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules diffe...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720578026242048 |
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| author | Khaledi, H. Ali, H.M. Abdulla, M.A. |
| author_facet | Khaledi, H. Ali, H.M. Abdulla, M.A. |
| author_sort | Khaledi, H. |
| collection | UM |
| description | The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules. |
| first_indexed | 2024-03-06T05:37:14Z |
| format | Article |
| id | um.eprints-14766 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:14Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-147662019-01-29T09:10:48Z http://eprints.um.edu.my/14766/ Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) Khaledi, H. Ali, H.M. Abdulla, M.A. QC Physics The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules. International Union of Crystallography 2010 Article PeerReviewed Khaledi, H. and Ali, H.M. and Abdulla, M.A. (2010) Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M351-U184. ISSN 1600-5368, |
| spellingShingle | QC Physics Khaledi, H. Ali, H.M. Abdulla, M.A. Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) |
| title | Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) |
| title_full | Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) |
| title_fullStr | Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) |
| title_full_unstemmed | Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) |
| title_short | Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) |
| title_sort | bis acetato kappa o 2 o diphenyl pyridine kappa n tin iv |
| topic | QC Physics |
| work_keys_str_mv | AT khaledih bisacetatokappao2odiphenylpyridinekappantiniv AT alihm bisacetatokappao2odiphenylpyridinekappantiniv AT abdullama bisacetatokappao2odiphenylpyridinekappantiniv |