(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H c...
| Main Authors: | , , , |
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946797621411840 |
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| author | Reisi, R. Misran, M. Lo, K.M. Ng, S.W. |
| author_facet | Reisi, R. Misran, M. Lo, K.M. Ng, S.W. |
| author_sort | Reisi, R. |
| collection | UM |
| description | The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H center dot center dot center dot O hydrogen bonding with the O atoms of adjacent molecules, generating a chain running along the c axis. |
| first_indexed | 2024-03-06T05:37:15Z |
| format | Article |
| id | um.eprints-14772 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:15Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-147722019-01-31T05:17:45Z http://eprints.um.edu.my/14772/ (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) Reisi, R. Misran, M. Lo, K.M. Ng, S.W. QC Physics The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H center dot center dot center dot O hydrogen bonding with the O atoms of adjacent molecules, generating a chain running along the c axis. International Union of Crystallography 2010 Article PeerReviewed Reisi, R. and Misran, M. and Lo, K.M. and Ng, S.W. (2010) (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M482-U1350. ISSN 1600-5368, |
| spellingShingle | QC Physics Reisi, R. Misran, M. Lo, K.M. Ng, S.W. (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) |
| title | (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) |
| title_full | (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) |
| title_fullStr | (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) |
| title_full_unstemmed | (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) |
| title_short | (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) |
| title_sort | 2 1 1 bis hydroxymethyl 2 oxidoethyl iminomethyl 4 chlorophenol ato kappa n 3 o o dibutyltin iv |
| topic | QC Physics |
| work_keys_str_mv | AT reisir 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappan3oodibutyltiniv AT misranm 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappan3oodibutyltiniv AT lokm 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappan3oodibutyltiniv AT ngsw 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappan3oodibutyltiniv |